(A) Schematic representation of the Hyp-GdEuC12 micelles and the respective structures of the amphiphilic GdLnC12 complex and the Hyp. (B) Overlay between the XEOL of EuCl3 (black line) and the absorption spectrum of Hyp (gray line). (C) 1O2 production of Hyp-GdEuC12 micelles as indicated by the abundance of 1-pyrenecarboxaldehyde, measured by mass spectrometry (∆: non-irradiated, □: irradiated). Adapted with permission from Ref 37. Copyright 2015 Springer. (D) Crystallographic structure of (n-Bu4N)2[Mo6I8(OOC-1-adamantane)6] (blue, molybdenum; magenta, iodine; red, oxygen; black, carbon; hydrogen atoms are omitted for clarity). (E) Scheme of (n-Bu4N)2[Mo6I8(OOC-1-adamantane)6] cluster-mediated X-PDT. Adapted with permission from Ref 39. Copyright 2015 American Chemical Society.