Table 5.
Biogeochemical Parameters
| Site | Bulk propertiesa | ||||||
|---|---|---|---|---|---|---|---|
| Organic carbon (%)d | Organic nitrogen (%)d | Oxygen penetration depth (cm)e | Total oxygen consumption (mmol−2 d−1)f | Chlorophyll (µg g−1)g | Zone of mixing (cm)h | Surface roughness (cm)h | |
| Benthic A |
1.12 ± 0.13 (0.98–1.34) |
0.13 ± 0.02 (0.10–0.17) |
0.875 ± 0.54 (0.3–1.6) |
−6.60 ± 3.82 (n = 30) (−13.46 to 9.80) |
1.43 ± 0.60 (0.68–2.1) |
6.28 ± 0.98 (3.69–7.30) |
1.85 ± 0.79 (0.92–3.20) |
| Benthic I |
0.58 ± 0.15 (0.39–0.84) |
0.09 ± 0.03 (0.04–0.14) |
0.725 ± 0.60 (0.20–1.50) |
−7.70 ± 3.97 (n = 24) (−19.13 to 3.17) |
0.47 ± 0.17 (0.22–0.6) |
5.23 ± 1.54 (3.32–8.01) |
1.83 ± 0.53 (1.20–3.30) |
| Benthic H |
0.42 ± 0.12 (0.31–0.65) |
0.07 ± 0.02 (0.04–0.11) |
0.875 ± 0.49 (0.3–1.5) |
−7.97 ± 2.64 (n = 30) (−13.62 to 2.39) |
0.42 ± 0.18 (0.3–0.64) |
4.55 ± 1.27 (3.05–7.47) |
1.82 ± 0.35 (1.25–2.46) |
| Benthic G |
0.22 ± 0.18 (0.11–0.49) |
0.06 ± 0.04 (0.02–0.12) |
2.08 ± 2.00 (0.5–5) |
−4.16 ± 2.82 (n = 28) (−11.02 to 0.66) |
0.33 ± 0.26 (0.08–0.62) |
n/a |
1.50 ± 0.89 (0.61–4.50) |
| Site | Porewater concentrations (µM)b | ||||||
|---|---|---|---|---|---|---|---|
| Nitrite (NO2 −) | TOxN (NO2 − + NO3 −) | Ammonium (NH4 +) | Silicate (SIO4 −) | Phosphate (PO4 3−) | Iron (Fe)i | Iron (Fe(II))i | |
| Benthic A | 0.46 ± 0.37 (0.07–8.27) | 4.45 ± 3.60 (0.33–12.8) | 38.3 ± 30.1 (0.29–144) | 134 ± 83.8 (5.72–339) | 7.61 ± 5.94 (0.93–28.4) | 4 ± 6 (0.1–10) | 3 ± 5 (0.08–9) |
| Benthic I | 0.58 ± 0.75 (0.10–3.14) | 4.26 ± 2.97 (0.20–17.9) | 38.3 ± 30.9 (0.23–145) | 146 ± 88.5 (3.14–358) | 7.55 ± 5.98 (0.25–29.0) | 7 ± 7 (3–15) | 12 ± 15 (3–29) |
| Benthic H | 0.78 ± 1.52 (0.09–1.74) | 4.63 ± 4.00 (0.08–9.2) | 38.6 ± 27.8 (0.29–107) | 145 ± 82.0 (5.39–347) | 7.68 ± 5.70 (0.86–25.7) | 0.5 ± 0.7 (0.11–1.3) | 0.5 ± 0.7 (0.1–1.3) |
| Benthic G | 0.74 ± 1.19 (0.09–2.87) | 4.47 ± 3.56 (0.19–16.6) | 40.3 ± 30.3 (0.55–114) | 153 ± 88.1 (5.93–368) | 7.47 ± 5.55 (1.08–21.2) | n/a | n/a |
| Site | Diffusive fluxes (mmol.m−2.d−1)c | |||||
|---|---|---|---|---|---|---|
| Nitrite (NO2 −) | TOxN (NO2 − + NO3 −) | Ammonium (NH4 +) | Silicate (SIO4 −) | Phosphate (PO4 3−) | Iron (Fe(II))j ×10−3 | |
| Benthic A | 0.013 ± 0.031 (−0.017 to 0.098) | 0.019 ± 0.174 (−0.212 to 0.499) | 0.021 ± 0.156 (−0.286 to 0.483) | 1.212 ± 0.679 (0.206 to 3.741) | −0.018 ± 0.024 (−0.063 to 0.028) | 14.4 ± 19.7 (−0.01 to 54.4) |
| Benthic I | 0.012 ± 0.021 (−0.007 to 0.064) | 0.125 ± 0.267 (−0.286 to 0.644) | −0.003 ± 0.145 (−0.077 to 0.380) | 0.646 ± 0.430 (−0.049 to 1.550) | 0.001 ± 0.029 (−0.080 to 0.054) | 8.30 ± 10.3 (0.23 to 32.8) |
| Benthic H | 0.011 ± 0.038 (−0.035 to 0.132) | 0.082 ± 0.286 (−0.586 to 0.649) | 0.049 ± 0.191 (−0.215 to 0.699) | 0.702 ± 0.612 (−0.287 to 2.016) | 0.004 ± 0.028 (−0.073 to 0.086) | 2.7 ± 5.47 (0.06 to 16.8) |
| Benthic G | 0.024 ± 0.030 (−0.008 to 0.105) | 0.059 ± 0.133 (−0.131 to 0.599) | 0.044 ± 0.023 (−0.257 to 0.319) | 0.531 ± 0.474 (−0.007 to 2.255) | 0.009 ± 0.035 (−0.085 to 0.070) | n/a |
Values are means of all samples collected at the sites, ± standard deviations (min–max ranges in brackets) and represent: a samples 0-5 cm in depth; b samples collected seasonally at the sites from triplicate porewater profiles (n = 9) representing 0–10 cm depth; cfluxes calculated at each site (n = 5–11) ± SD (min–max ranges in brackets). d Kirsten (1979), eMeasured immediately from 20 cm diameter cores, sub-sampled from NIOZ box cores, Cai and Sayles (1996); f Glud (2008), Hicks et al. (2017), Smith et al. (in prep); g Measured using spectrophotometry (for DY008, HMSO (1980)) or fluorescence (Tett 1987); h Derived from SPI, Solan et al. (2004); i Iron values are for surface (0–2 cm) only: not measured at Benthic G; j Homoky et al. (2012)