Table 1.
Position | 1 | 2 | ||
---|---|---|---|---|
δ H | δ C | δ H | δ C | |
1 | 127.0 | 127.3 | ||
2 | 7.01 d (1.5) | 109.2 | 7.74 d (2.0) | 112.6 |
3 | 146.5 | 145.9 | ||
4 | 147.9 | 147.0 | ||
5 | 6.89 d (8.0) | 114.6 | 6.86 d (8.0) | 113.7 |
6 | 7.05 dd (1.5, 8.0) | 123.1 | 7.08 dd (2.0, 8.0) | 125.5 |
7 | 7.58 d (16.0) | 114.6 | 6.77 d (13.0) | 143.7 |
8 | 6.27 d (16.0) | 115.6 | 5.79 d (13.0) | 116.8 |
9 | 167.3 | 166.7 | ||
1′ | 4.16 t (7.0) | 64.4 | 4.09 t (7.0) | 64.4 |
2′ | 1.37 m | 28.6 | 1.30 m | 28.5 |
3′ | 1.67 m | 25.9 | 1.62 m | 25.8 |
4′ | n.d.b | n.d. b | ||
5′ | 1.23 s | 29.5 | 1.23 s | 29.5 |
6′ | 1.23 s | 29.5 | 1.23 s | 29.5 |
–OCH3 | 3.91 s | 55.6 | 3.91 s | 55.6 |
aJ values are in parentheses and reported in Hz; 13C NMR assignments are based on 1H-1H COSY, HSQC, and HMBC experiments; b not detected.