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. 2019 Dec 31;5(1):197–206. doi: 10.1021/acsomega.9b02448

Table 2. Correlation between the Absorption Difference Δν and the Extractability.

  C=O absorption banda (cm–1)
extractabilityd
plasticizer νob νc |Δν̅| (wt %)
DOP 1724 1720 4.0 14.1%
2,5-DBF 1724, 1709 1736, 1717 10.0 13.5%
2,5-DIAF 1724, 1709 1736, 1718 10.5 13.1%
2,3-DIAF 1712 1722 10.0 7.9%
2,3-DBF 1716 1730 14.0 5.4%
a

Apparatus’ resolution: 4 cm–1.

b

Frequency of unbound C=O stretching band (pure form, before mixing).

c

Frequency of interactive C=O stretching band (PVC-PLS 50%, after mixing).

d

Extraction resistance (ASTM D5227-13): the lower the value, the higher the polarity.