Table 2. Correlation between the Absorption Difference Δν and the Extractability.
C=O
absorption banda (cm–1) |
extractabilityd | |||
---|---|---|---|---|
plasticizer | νob | νc | |Δν̅| ↓ | ↑ (wt %) |
DOP | 1724 | 1720 | 4.0 | 14.1% |
2,5-DBF | 1724, 1709 | 1736, 1717 | 10.0 | 13.5% |
2,5-DIAF | 1724, 1709 | 1736, 1718 | 10.5 | 13.1% |
2,3-DIAF | 1712 | 1722 | 10.0 | 7.9% |
2,3-DBF | 1716 | 1730 | 14.0 | 5.4% |
Apparatus’ resolution: 4 cm–1.
Frequency of unbound C=O stretching band (pure form, before mixing).
Frequency of interactive C=O stretching band (PVC-PLS 50%, after mixing).
Extraction resistance (ASTM D5227-13): the lower the value, the higher the polarity.