Table 2. Nuclear Magnetic Resonance (NMR) Spectroscopic Data (600 MHz, DMSO) for 5 and 6.
5 | 6 | |||
---|---|---|---|---|
position | δC | δH (J in Hz) | δC | δH (J in Hz) |
1 | 158.9 | 14.18, s | 158.0 | |
2 | 103.4 | 110.6 | ||
3 | 157.1 | 162.4 | ||
4 | 93.6 | 6.32, s | 104.3 | |
4a | 155.6 | 152.6 | ||
5 | 100.0 | 6.73, s | 147.6 | |
6 | 152.1 | 11.18, s | 120.6 | 7.28, dd (7.8, 1.3) |
7 | 141.0 | 8.69, s | 124.0 | 7.24, t (7.8) |
8 | 129.9 | 114.6 | 7.55, dd (7.8, 1.3) | |
8a | 110.1 | 120.3 | ||
9 | 181.7 | 180.8 | ||
9a | 102.9 | 102.2 | ||
10a | 152.8 | 146.5 | ||
11 | 114.8 | 6.60, d (10.0) | 21.4 | 3.28, d (7.0) |
12 | 127.8 | 5.72, d (10.0) | 122.4 | 5.18, d (7.4) |
13 | 77.9 | 130.8 | ||
14 | 29.1 | 1.20, s | 25.6 | 1.61, s |
15 | 29.1 | 1.20, s | 17.9 | 1.67, s |
16 | 43.6 | 1.57, m | 29.2 | 3.21, dd (14.7, 3.2), 3.03, dd (14.8, 7.7) |
17 | 21.9 | 3.30, dd (9.7, 6.8) | 74.6 | 4.32, m |
18 | 69.3 | 1.3, s | 144.9 | |
19 | 27.9 | 1.42, s | 109.8 | 4.86, s; 4.72, s |
20 | 27.9 | 1.42, s | 18.5 | 1.81, s |