Table 5.

Mass/charge relation of each polyphenolic compound analized in the geopropolis samples.

Polyphenolic compound	Parent íon (m/z) - Q1	Quantitative íon (m/z) - Q3	Retention time (min)
Gallic ac	168.908	125	3.98
Protocatechuic ac	152.921	109	6.95
Mandelic ac	150.996	107	7.86
Catechin	289.045	109	8.82
4-(Hydroxymethyl)benzoic ac	150.967	107	8.84
Chlorogenic ac	353.155	191	9.19
Epicatechin	288.954	109	9.41
Caffeic ac	178.927	135	9.45
Vanillic ac	166.923	108	9.65
Syringic ac	196.939	121.1	10.01
Epicatechin gallate	441.6	168.9	10.15
Fustin	286.969	109	10.32
Vanilin	150.958	136	10.42
p-Coumaric ac	162.926	119.1	10.46
4-aminobenzoic ac	135.995	91.9	10.47
α-Methoxyphenylacetic ac	164.976	121.1	10.51
Taxifolin	303.019	125.1	10.7
Rutin	609.242	300.1	10.72
Ferulic ac	192.957	134	10.73
Syringaldehyde	180.94	151	10.76
Umbelliferone	160.941	133.1	10.78
Rosmarinic ac	359.082	161	10.83
Isoquercitrin	463.155	300	10.83
Quercetin	300.968	151	10.84
Sinapic ac	223.011	148.8	10.87
Salicylic ac	136.942	93	10.99
Escopoletin	190.972	176	10.99
Resveratrol	226.999	142.9	11.14
Naringin	580.276	151	11.18
Miricetrin	316.995	151	11.24
Aromadendrin	287.004	125	11.29
Coniferaldehyde	177.015	162	11.31
p-Anisic ac	150.947	136	11.34
Sinapaldehyde	207.04	177	11.39
Ellagic ac	300.959	145	11.71
Cinnamic ac	146.952	102.9	11.8
Eriodictyol	186.97	151	11.85
Kaempferol	284.995	93	12.34
Naringenin	270.985	151.1	12.37
Apigenin	268.992	117.1	12.62
Hispidulin	298.957	284	12.72
Galangin	268.981	117	13.44
Pinocembrin	255.051	65	13.59
Chrysin	252.988	62.9	13.88
Carnosol	329.167	285.2	14.32