Table 1.

Photoredox catalytic pentafluorosulfanylations of 2 to the methoxylated 9.

Entry	Conditions[a]	[2] [m]	MeOH [equiv]	Yield [%]
1	365 nm	0.10	5	29
2	365 nm	0.10	10	44
3	365 nm	0.20	10	53
4	no light	0.10	10	no reaction
5	no catalyst	0.10	10	no reaction

[a] General reaction conditions: 20 mol % BEt₃, 20 °C, 2.8 bar SF₆, 368 nm, 22 h in MeCN. Yields determined by GC‐FID.