Table 2. Ether–MOF and phenol–MOF binding energies (kJ mol–1, 0 K) predicted by DFT/SCAN.
IRMOF-74(I)Mg | IRMOF-74(II)Mg | IRMOF-74(III)Mg | IRMOF-74(IV)Mg | |
DPE | 59.7 | 59.1 | 94.7 | 55.8 |
BPE | 63.4 | 69.1 | 99.8 | 65.6 |
PPE | 64.2 | 73.6 | 98.1 | 71.0 |
Phenol | 63.7 | 75.4 | 117.3 | 69.1 |