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. 2019 Jul 4;27(7):930–938. doi: 10.1016/j.jsps.2019.07.001

Table 3.

Identified compounds by LC-MS/MS analysis of the active plant extracts.

RT [M-H]m/z Fragments Identified compounds
H. officinalis leaves & stems EtOH extract # 29
8.0 353 191, 179 3-caffeoylquinic acid
9.7 637 351, 285 luteolin diglucuronide
9.9 447 285 luteolin glucoside
9.9 609 301, 271, 255, 179 quercetin 7-rutinoside
10.5 637 461, 285 leukoseptoside A
11.1 621 487, 351, 269 apigenin derivative
11.4 461 285 luteolin glucuronide
12.6 445 269, 175, 113 apigenin glucuronide
13.1 359 197, 179, 161 rosmarinic acid
16.3 285 175, 133 luteolin



N. sativa seeds MeOH extract # 34
3.5 286 162 unknown
4.9 267 249 unknown
5.3 289 199, 169, 127 unknown
6.8 401 283, 269 apigenin pentoside
7.7 353 191, 179, 161 5-caffeoylquinic acid
7.9 771 609, 429, 284 luteolin / Kaempferol-sophoroside-glucoside



O. tenuiflorum leaves & stems MeOH extract # 36
7.7 341 179 caffeoyl glucoside
9.4 609 300, 271, 179, 151 rutin
10.4 463 300, 271, 179, 151 quercetin glucuronide
13.2 539 471, 377, 307, 275 unknown
13.9 359 197, 179, 161 rosmarinic acid
18.0 581 461, 436 unknown
27.5 343 328, 313, 241 nevadensin
27.8 283 240, 215 acacetin/ wogonin
30.6 555 487, 469, 425 unknown
33.6 293 275, 235, 231, 171 unknown



S. lappa root EtOH extract # 50
9.2 353 191, 173 5-caffeoylquinic acid
12.3 515 352, 191, 179, 161 1,5-dicaffeoylquinic acid
12.4 515 353, 299, 203, 191, 179 4,5-dicaffeoylquinic acid
13.2 561 369, 351, 215, 191 feruloyl quinic acid derivative
14.3 313 298, 283, 265 dihydroxy-dimethoxyflavone similar to cirsimaritin
15.1 431 268 apigenin glucoside



T. officinale leaves & stems EtOH extract # 53
6.0 341 179, 161 caffeoyl glucoside
9.1 191 173, 127 quinic acid
9.9 447 357, 327 luteolin-6-C-glucoside
10.0 179 135 caffeic acid
11.1 477 301, 179, 151 quercetin glucuronide
11.3 198 163 unknown
12.1 461 285 luteolin glucuronide
14.5 473 293, 219, 179, 161 cichoric acid
15.9 285 199, 151, 133 luteolin
17.9 269 201, 151, 117 apigenin