Table 1. Properties of Compounds HL3, HL7, HL9, and Reference Explosives.
compound | Tda | ρb (g cm–3) | ΔHfc (kJ mol–1) | VODd (m s–1) | Pe (GPa) | ISf (J) | FSg (N) | ESDh (J) |
---|---|---|---|---|---|---|---|---|
HL3 | 351 | 1.805 | 184.3 | 8,234 | 28.6 | 10 | 352 | 1.12 |
HL7 | 341 | 1.865 | 446.5 | 8,517 | 30.6 | 22 | 352 | 1.05 |
HL9 | 262 | 1.810 | 224.2 | 8,357 | 29.7 | 14 | 352 | 0.98 |
HNS | 318 | 1.740 | 78.2 | 7,612 | 24.3 | 5 | 240 | 0.8 |
LLM-105 | 345 | 1.910 | –12.0 | 8,560 | 33.4 | 28 | >360 | 1.02 |
Onset decomposition temperature by DSC (heating rate of 5 °C min–1).
Density measured by helium gas pycnometer (at 25 °C).
Calculated standard molar enthalpy of formation.
Calculated velocity of detonation.
Calculated detonation pressure.
Impact sensitivity evaluated by a drop hammer (2.5 kg) BAM technique.
Friction sensitivity evaluated by a BAM technique.
Electrostatic discharge sensitivity.