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. 2019 Aug 20;10(41):9513–9529. doi: 10.1039/c9sc02526j

Table 5. Measured second order rate constants for the reaction of 0.25 mM solutions of 1(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 NTs and 2(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 NTs with selected XPhSMe at 293 K.

XPhSMe k′ (×10–3 M–1 s–1)
[1(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 NTs] [1(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 O] [2(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 NTs] [2(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 O] a [3(IV) Created by potrace 1.16, written by Peter Selinger 2001-2019 NTs]
CH3O 77 ± 10 260 ± 9 207 ± 14 400 ± 20 6794
CH3 20 ± 3 126 ± 3 49 ± 1.0 201 ± 4 1560
H 12 ± 2 50 ± 2 7.9 ± 0.8 91 ± 4 260
Cl 1.6 ± 0.3 29 ± 3 2.2 ± 0.5 42 ± 4 139

aData from ref. 47, 1 mM solutions at 273 K.