Table 2.
Number of moles sorbed (Nf), parameters of the Langmuir (Ns and b), correlation coefficients (r), and standard errors (SE) for the interaction of divalent metals with modified chitosan CH-AN at 298 ± 1 K using linear method.
Isotherm | Constant | Type I | Type II | Type III | Type IV |
---|---|---|---|---|---|
Cu2+ | Nf (mmol g−1) | 2.02 | 2.02 | 2.02 | 2.02 |
Ns (mmol g−1) | 2.83 ± 0.02 | 2.82 ± 0.01 | 2.83 ± 0.02 | 2.84 ± 0.01 | |
b (g mmol−1) | 0.30 ± 0.01 | 0.30 ± 0.01 | 0.30 ± 0.05 | 0.30 ± 0.01 | |
R2 | 0.998 | 0.999 | 0.997 | 0.997 | |
SE | 0.019 | 0.019 | 0.019 | 0.019 | |
χ2 | 0.001 | 0.001 | 0.001 | 0.001 | |
Pb2+ | Nf (mmol g−1) | 2.54 | 2.54 | 2.54 | 2.54 |
Ns (mmol g−1) | 2.99 ± 0.03 | 2.99 ± 0.03 | 2.99 ± 0.03 | 2.99 ± 0.03 | |
b (g mmol−1) | 0.31 ± 0.01 | 0.31 ± 0.01 | 0.31 ± 0.01 | 0.31 ± 0.01 | |
R2 | 0.998 | 0.998 | 0.998 | 0.998 | |
SE | 0.032 | 0.032 | 0.032 | 0.032 | |
χ2 | 0.005 | 0.005 | 0.005 | 0.005 |