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. 2020 Jan 6;25(1):225. doi: 10.3390/molecules25010225

Table 2.

First order degradation rates (k [1/day]) obtained during shelf-life experiment for the identified anthocyanins in the strawberry extract stored at 4 °C, 25 °C and 37 °C and their activation energies (Ea [KJ/mol]) (citric buffer pH = 3, 50 mM).

k [1/day] Ea [kJ/mol]
Storage Temperature 4 °C 25 °C 37 °C
Compound Name
Pelargonidin-3-O-glucoside 0.0089 ± 0.0007 a, A 0.05 ± 0.01 b, A 0.274 ± 0.007 c, A 71.5 ± 14.3 A
Pelargonidin-3-O-rutinoside 0.007 ± 0.001 a, B 0.034 ± 0.007 b, B 0.21 ± 0.01 c, B 70.3 ± 17.0 A
Cyanidin-3-O-glucoside 0.010 ± 0.003 a, AB 0.040 ± 0.008 b, A 0.250 ± 0.005 c, AB 66.7 ± 17.9 A
5-Pyranopelargonidin-3-O-glucoside 0.0003 ± 0.00011a, C 0.002 ± 0.009 a, C 0.015 ± 0.004 b, C 105.2 ± 8.8 B
Pelargonidin-3-O-malonylglucoside 0.0105 ± 0.0009 a, D 0.07 ± 0.02 b, A 0.35 ± 0.01 c, D 73.6 ± 11.2 A

* Values with different letters indicate significant (p < 0.05) differences. Small letters represent differences in rows (effect of temperature for the same compound) and capital letters for columns (differences between structurally different anthocyanins). * Significant increase in degradation rates of 5-pyranopelatgonidin-3-O-glucoside was observed only between 37 °C to 4 °C and 25 °C, thus Ea is calculated but is more prone to errors.