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. 2019 Sep 24;10(44):10366–10372. doi: 10.1039/c9sc03758f

Table 2. Oxidation of (RN4)NiII(cycloneophyl) with various oxidants in MeCN.

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Complex Yield a (%)
PhI(OAc)2 NFTPT TDTT XeF2
1 4; 22 17; 39 7; 19 20; 40
2 24; 13 32; 27 33; 15 50; 16
3 42; 10 96; 4 42; 9 99; 1
4 ND b 14; 44 6; 9 ND b

aReaction conditions: MeCN, 70 °C, 14 h. Yields (%) were determined by GC-FID vs. 1,3,5-trimethoxybenzene as internal standard. The first yield shown is for 1,1-dimethylbenzocyclobutene, while the second yield is for is tert-butylbenzene.

bNot determined.