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Optimized gas-phase geometries for androsterone and trans-androsterone as their sodiated dimers where the sodium is adducted between two ketones, one ketone and one alcohol, and two alcohols. The lowest energy structures are for between two ketones for trans-androsterone and between one ketone and one alcohol for androsterone. Reproduced with permission from Chouinard et al. [12], copyright 2016 American Society for Mass Spectrometry.
