Table 1.
Days | Parent substance | Metabolites | |
---|---|---|---|
clethodim | sulfone | sulfoxide | |
Mean C ± SD n = 3 | Mean C ± SD n = 3 | Mean C ± SD n = 3 | |
BASIL Ocimum basilicum L. | |||
0 (1 h) | 3.897 ± 0.0034 | 0.246 ± 0.0056 | 1.965 ± 0.0046 |
1 | 0.728 ± 0.0028 | 0.504 ± 0.0061 | 1.257 ± 0.0035 |
2 | 0.459 ± 0.0046 | 0.493 ± 0.0021 | 0.787 ± 0.0043 |
3 | 0.293 ± 0.0054 | 0.305 ± 0.0029 | 0.505 ± 0.0028 |
7 | 0.270 ± 0.0019 | 0.239 ± 0.0017 | 0.299 ± 0.0019 |
14 | 0.251 ± 0.0022 | 0.105 ± 0.0026 | 0.220 ± 0.0015 |
21 | 0.151 ± 0.0030 | 0.046 ± 0.0010 | 0.139 ± 0.0011 |
PEPPERMINT Mentha × piperita L. | |||
0 (1 h) | 4.251 ± 0.0042 | 0.220 ± 0.0036 | 1.948 ± 0.0068 |
1 | 0.203 ± 0.0028 | 0.316 ± 0.0025 | 0.602 ± 0.0044 |
2 | 0.198 ± 0.0033 | 0.492 ± 0.0029 | 0.310 ± 0.0026 |
3 | 0.175 ± 0.0019 | 0.318 ± 0.0031 | 0.373 ± 0.0031 |
7 | 0.084 ± 0.0023 | 0.150 ± 0.0016 | 0.136 ± 0.0027 |
14 | 0.060 ± 0.0017 | 0.079 ± 0.0013 | 0.078 ± 0.0014 |
21 | <LOQ | 0.033 ± 0.0009 | 0.022 ± 0.0008 |
SAGE Salvia officinalis L. | |||
0 (1 h) | 4.197 ± 0.0048 | 0.221 ± 0.0060 | 2.437 ± 0.0055 |
1 | 0.983 ± 0.0052 | 0.253 ± 0.0042 | 0.304 ± 0.0021 |
2 | 0.917 ± 0.0035 | 0.431 ± 0.0021 | 0.112 ± 0.0032 |
3 | 0.444 ± 0.0031 | 0.328 ± 0.0044 | 0.064 ± 0.0011 |
7 | 0.447 ± 0.0014 | 0.302 ± 0.0020 | 0.026 ± 0.0018 |
14 | <LOQ | 0.204 ± 0.0031 | 0.009 ± 0.0012 |
21 | <LOQ | 0.086 ± 0.0012 | 0.006 ± 0.0011 |
Mean C – concentration for n = 3 (mg/kg) ±SD – standard deviation (mg/kg), LOQ – limit of quantification (mg/kg).