Table 2.
Days after treatment | Parent substance | Metabolites | |||
---|---|---|---|---|---|
Spirotetramat (SPI) | SPI-enol | SPI-ketohydroxy | SPI-monohydroxy | SPI-enol-glucoside | |
Mean C ± SD n = 3 | Mean C ± SD n = 3 | Mean C ± SD n = 3 | Mean C ± SD n = 3 | Mean C ± SD n = 3 | |
BASIL Ocimum basilicum L. | |||||
0 (1 h) | 3.619 ± 0.0056 | 1.952 ± 0.0061 | 0.162 ± 0.0020 | 0.008 ± 0.0003 | 0.007 ± 0.0002 |
1 | 1.968 ± 0.0049 | 1.280 ± 0.0050 | 0.359 ± 0.0036 | 0.006 ± 0.0002 | 0.037 ± 0.0011 |
2 | 2.033 ± 0.0051 | 0.814 ± 0.0048 | 0.495 ± 0.0065 | <LOQ | 0.067 ± 0.0022 |
3 | 0.447 ± 0.0036 | 0.542 ± 0.0032 | 0.416 ± 0.0041 | <LOQ | 0.063 ± 0.0013 |
7 | 0.024 ± 0.0021 | 0.184 ± 0.0024 | 0.237 ± 0.0035 | <LOQ | 0.081 ± 0.0025 |
14 | 0.010 ± 0.0012 | 0.044 ± 0.0021 | 0.193 ± 0.0023 | <LOQ | 0.061 ± 0.0039 |
21 | 0.002 ± 0.0005 | 0.027 ± 0.0009 | 0.095 ± 0.0014 | <LOQ | 0.072 ± 0.0026 |
PEPPERMINT Mentha × piperita L. | |||||
0 (1 h) | 3.830 ± 0.0060 | 2.221 ± 0.0053 | 0.076 ± 0.0038 | 0.006 ± 0.0001 | 0.014 ± 0.0004 |
1 | 2.530 ± 0.0051 | 0.683 ± 0.0024 | 0.779 ± 0.0051 | 0.006 ± 0.0002 | 0.011 ± 0.0002 |
2 | 3.330 ± 0.0047 | 0.238 ± 0.0032 | 0.666 ± 0.0048 | <LOQ | 0.005 ± 0.0001 |
3 | 0.733 ± 0.0022 | 0.269 ± 0.0019 | 0.588 ± 0.0034 | <LOQ | 0.065 ± 0.0008 |
7 | 0.020 ± 0.0008 | 0.011 ± 0.0002 | 0.041 ± 0.0025 | <LOQ | 0.034 ± 0.0003 |
14 | 0.008 ± 0.0003 | <LOQ | 0.009 ± 0.0002 | <LOQ | 0.037 ± 0.0004 |
21 | 0.004 ± 0.0002 | <LOQ | 0.010 ± 0.0003 | <LOQ | 0.015 ± 0.0002 |
SAGE Salvia officinalis L. | |||||
0 (1 h) | 3.904 ± 0.0069 | 1.868 ± 0.0033 | 0.077 ± 0.0008 | 0.010 ± 0.0003 | 0.006 ± 0.0002 |
1 | 3.001 ± 0.0065 | 0.699 ± 0.0026 | 0.538 ± 0.0058 | 0.007 ± 0.0002 | 0.005 ± 0.0001 |
2 | 2.795 ± 0.0051 | 0.689 ± 0.0024 | 0.500 ± 0.0052 | <LOQ | 0.006 ± 0.0001 |
3 | 0.710 ± 0.0013 | 0.178 ± 0.0016 | 0.418 ± 0.0021 | <LOQ | <LOQ |
7 | 0.134 ± 0.0011 | 0.161 ± 0.0017 | 0.091 ± 0.0012 | <LOQ | <LOQ |
14 | 0.097 ± 0.0009 | 0.198 ± 0.0019 | 0.048 ± 0.0011 | <LOQ | <LOQ |
21 | 0.042 ± 0.0006 | 0.041 ± 0.0008 | 0.039 ± 0.0009 | <LOQ | <LOQ |
Mean C – mean concentration for n = 3 (mg/kg) ± SD – standard deviation (mg/kg), LOQ – limit of quantification (mg/kg).