Table 2.
Comparison between the FBS and the CSTR: 1. FBS with H2O2 concentration not constant, 2. nearly constant, 3. CSTR H2O2 concentration constant. Hydrogen peroxide influent concentration, specific reaction rate ṙ, time when deactivation was significant td, amount of product formed , catalytic productivity Pcat, yield Y. To compare the process set‐ups, the space‐time yield STY of the FBS was calculated in the initial part of the reaction
Operation | Results | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
No |
|
ṙ | td | NPOA | Pcat | Y | STY | |||
[mM] | [mmol h−1g−1] | [h] | [mmol] | [mmol g−1] | [%] | [mmol L−1 h−1] | ||||
start | end | |||||||||
1 | FBS | 80 | 5.6 | 36 | 6 | 58 | 128 | 96 | 49 | |
2 | 110 | 105 | 27 | 2 | 21 | 46 | 11 | 36 | ||
3 | CSTR | 97 | 3 | 55 | 425 | 213 | 90 | 154 |