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. Author manuscript; available in PMC: 2020 Jul 15.
Published in final edited form as: J Am Chem Soc. 2020 Jan 3;142(2):710–714. doi: 10.1021/jacs.9b13046

Figure 3.

Figure 3.

Biosynthesis of the core of 1. (A) LC-MS analysis of metabolites in vivo and in vitro assays; (B) Crystal structure of 10a; (C) Proposed biosynthetic pathway of 3. Observed shunt products are shown in the dashed box.