| Crystal data |
| Chemical formula |
[PtCl(C4H10AsN2O4)] |
[Pt(C6H14AsN2O4)Cl] |
|
M
r
|
455.59 |
483.65 |
| Crystal system, space group |
Triclinic, P
|
Monoclinic, P21/c
|
| Temperature (K) |
100 |
100 |
|
a, b, c (Å) |
7.272 (1), 8.099 (1), 9.350 (2) |
8.9009 (3), 14.1270 (5), 9.6438 (3) |
| α, β, γ (°) |
66.588 (5), 83.993 (5), 76.737 (5) |
90, 98.243 (2), 90 |
|
V (Å3) |
491.81 (14) |
1200.11 (9) |
|
Z
|
2 |
4 |
| Radiation type |
Mo Kα |
Mo Kα |
| μ (mm−1) |
17.86 |
14.65 |
| Crystal size (mm) |
0.39 × 0.29 × 0.14 |
0.55 × 0.42 × 0.08 |
| |
| Data collection |
| Diffractometer |
Bruker APEXII CCD |
Bruker APEXII CCD |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2012 ▸) |
Multi-scan (SADABS; Bruker, 2012 ▸) |
|
T
min, T
max
|
0.003, 0.090 |
0.001, 0.301 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
8305, 2435, 2345 |
41298, 2891, 2700 |
|
R
int
|
0.039 |
0.047 |
| (sin θ/λ)max (Å−1) |
0.667 |
0.661 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.020, 0.052, 1.18 |
0.022, 0.081, 1.05 |
| No. of reflections |
2411 |
2891 |
| No. of parameters |
136 |
148 |
| No. of restraints |
4 |
1 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.79, −2.05 |
1.53, −1.98 |
