Skip to main content
. 2019 Sep 4;10(43):10003–10009. doi: 10.1039/c9sc03694f

Fig. 2. UV/Vis spectra of (a) ionic (rac)-2 and (b) non-ionic (rac)-2Ac in different oxidation states. Isosbestic points indicating a clean transition from TTF˙+ to TTF2+ are highlighted with red circles. Spectra were obtained with 25 μM solutions in CH2Cl2 using bulk Fe(ClO4)3 as the oxidant; (c) correlation diagram of half-wave potentials obtained by cyclic voltammetry for the first and second redox process of (rac)-2, dTTFC8 and (rac)-2Ac (each 1 mM) in CH2Cl2 referenced against Fe(Cp)20/+ with NBu4PF6 (0.1 M) as the electrolyte.

Fig. 2