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. 2019 Feb 6;10(4):793–798. doi: 10.1021/acs.jpclett.8b03646

Table 1. Exciplex Photophysical Properties at Different Dilutions in UGH-3 or DPEPO.

dilution vol % average D–A distance (Å) τDF (μs) PL onset (eV) PL fwhm (eV) PLQY air/N2
neat exciplex 0 6.0 2.4 ± 0.1 2.67 0.51 0.45/0.58
UGH-3 10 6.3 2.2 ± 0.1 2.68 0.52 0.50/0.63
UGH-3 30 6.8 2.8 ± 0.1 2.70 0.51 0.51/0.65
UGH-3 50 7.6 3.1 ± 0.1 2.79 0.58 0.67/0.80
UGH-3 70 9.0 3.1 ± 0.2 2.83 0.58 0.49/0.70
UGH-3 90 13   2.85 0.48 0.35/0.35
DPEPO 10 6.3 2.4 ± 0.1 2.67   0.52/0.68
DPEPO 30 6.8 2.5 ± 0.1 2.67   0.34/0.45
DPEPO 50 7.6 2.3 ± 0.1 2.70   0.23/0.28
DPEPO 70 9.0 2.9 ± 0.1 2.73   0.28/0.38
DPEPO 90 13 2.8 ± 0.1 2.80   0.06/0.07