Table 1. Exciplex Photophysical Properties at Different Dilutions in UGH-3 or DPEPO.
dilution | vol % | average D–A distance (Å) | τDF (μs) | PL onset (eV) | PL fwhm (eV) | PLQY air/N2 |
---|---|---|---|---|---|---|
neat exciplex | 0 | 6.0 | 2.4 ± 0.1 | 2.67 | 0.51 | 0.45/0.58 |
UGH-3 | 10 | 6.3 | 2.2 ± 0.1 | 2.68 | 0.52 | 0.50/0.63 |
UGH-3 | 30 | 6.8 | 2.8 ± 0.1 | 2.70 | 0.51 | 0.51/0.65 |
UGH-3 | 50 | 7.6 | 3.1 ± 0.1 | 2.79 | 0.58 | 0.67/0.80 |
UGH-3 | 70 | 9.0 | 3.1 ± 0.2 | 2.83 | 0.58 | 0.49/0.70 |
UGH-3 | 90 | 13 | 2.85 | 0.48 | 0.35/0.35 | |
DPEPO | 10 | 6.3 | 2.4 ± 0.1 | 2.67 | 0.52/0.68 | |
DPEPO | 30 | 6.8 | 2.5 ± 0.1 | 2.67 | 0.34/0.45 | |
DPEPO | 50 | 7.6 | 2.3 ± 0.1 | 2.70 | 0.23/0.28 | |
DPEPO | 70 | 9.0 | 2.9 ± 0.1 | 2.73 | 0.28/0.38 | |
DPEPO | 90 | 13 | 2.8 ± 0.1 | 2.80 | 0.06/0.07 |