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. 2019 May 29;9(7):6087–6099. doi: 10.1021/acscatal.9b01266

Table 2. Redox Potentials of T1Cu, T2Cu, and Haem Centers in the Various CuNiR Proteinsa.

construct Haem (mV) vs SHE T1Cu (mV) vs SHE T2Cu (mV) vs SHE
full-length RpNiR 290 ± 1 266 ± 2 255 ± 4
RpNiR cyt c 290 ± 1 n/a n/a
RpNiR-core n/a 331 ± 5 243 ± 3
Y323F RpNiR-core n/a 338 ± 7 257 ± 8
AxNiR n/a 255 ± 3b 244 ± 18b
Axcyt c551 233 ± 1 n/a n/a
a

Data are shown ± error of fit.

b

Data for AxNiR T1Cu and T2Cu centers are taken from Leferink et al.13