Table 2. Redox Potentials of T1Cu, T2Cu, and Haem Centers in the Various CuNiR Proteinsa.
construct | Haem (mV) vs SHE | T1Cu (mV) vs SHE | T2Cu (mV) vs SHE |
---|---|---|---|
full-length RpNiR | 290 ± 1 | 266 ± 2 | 255 ± 4 |
RpNiR cyt c | 290 ± 1 | n/a | n/a |
RpNiR-core | n/a | 331 ± 5 | 243 ± 3 |
Y323F RpNiR-core | n/a | 338 ± 7 | 257 ± 8 |
AxNiR | n/a | 255 ± 3b | 244 ± 18b |
Axcyt c551 | 233 ± 1 | n/a | n/a |
Data are shown ± error of fit.
Data for AxNiR T1Cu and T2Cu centers are taken from Leferink et al.13