Table 12.
Specifications for acetylated oxidised starch (E 1451) according to Commission Regulation (EU) No 231/2012 and JECFA (2016a)
| Commission Regulation (EU) No 231/2012 | JECFA (2016a) | |
|---|---|---|
| Definition | Acetylated oxidised starch is starch treated with sodium hypochlorite followed by esterification with acetic anhydride | Acetylated oxidised starch is a modified starch. It is obtained by treatment of food starch with sodium hypochlorite followed by esterification with acetic anhydride in accordance with good manufacturing practice. Oxidation involves the deliberate production of carboxyl groups. Acetylation results in substitution of hydroxyl groups with acetyl esters. Acetylated oxidised starch may additionally be subjected to acid, alkali, enzyme or bleaching treatment in accordance with good manufacturing practice |
| Description | White or nearly white powder or granules or (if pregelatinised) flakes, amorphous powder or coarse particles | White or nearly white powder or granules or (if pregelatinised) flakes, or amorphous powder or coarse particles |
| Identification | ||
| Microscopic observation | Passes test (if not pregelatinised) | Passes test |
| Iodine staining | Passes test (dark blue to light red colour) | Passes test |
| Solubility | − | Insoluble in cold water (if not pregelatinised); forming typical colloidal solutions with viscous properties in hot water; insoluble in ethanol |
| Copper reduction | − | Passes test |
| Hypochlorite oxidised starch | − | Passes test |
| Specific reaction for acetyl groups | − | Passes test |
| Ester groups | − | Passes test |
| Purity | ||
| Loss on drying |
Not more than 15.0% for cereal starch Not more than 21.0% for potato starch Not more than 18.0% for other starches |
Cereal starch: not more than 15.0% Potato starch: not more than 21.0% Other starches: not more than 18.0% (120°, 4 h, vacuum not exceeding 100 mmHg) |
| Carboxyl groups | Not more than 1.3% (on an anhydrous basis) | Not more than 1.3% on the dried basis |
| Acetyl groups | Not more than 2.5% (on an anhydrous basis) | Not more than 2.5% on the dried basis |
| Sulfur dioxide |
Not more than 50 mg/kg for modified cereal starches (on an anhydrous basis) Not more than 10 mg/kg for other modified starches, unless otherwise specified (on an anhydrous basis) |
Not more than 50 mg/kg on the dried basis for modified cereal starches Not more than 10 mg/kg on the dried basis for other modified starches |
| Arsenic | Not more than 1 mg/kg | − |
| Lead | Not more than 2 mg/kg (on an anhydrous basis) | Not more than 2 mg/kg on the dried basis |
| Mercury | Not more than 0.1 mg/kg | − |
| Manganese | − | Not more than 50 mg/kg on the dried basis |