Skip to main content
. 2019 Apr 25;9(6):5268–5278. doi: 10.1021/acscatal.9b00918

Table 4. H/D Exchange Experiments of 1ea.

2.4.1.

Entry Conditions d1-1e (%)a
1 Standard conditions without Ag2CO3 0
2 0.65 equiv Ag2CO3 0
3 0.65 equiv Ag2CO3, 5.5 mol % (R)-L10 0
4 0.65 equiv Ag2CO3, 5.5 mol % (R)-L10, 0.5 equiv Cy2CHCO2H 0
5 0.65 equiv Ag2CO3, 2 equiv TMP 32
6 0.65 equiv Ag2CO3, 5.5 mol % (R)-L10, 2 equiv TMP 54
7 0.65 equiv Ag2CO3, 5.5 mol % (R)-L10, 0.5 equiv Cy2CHCO2H, 2 equiv TMP 48
a

Determined by 1H NMR spectroscopy using 1,3,5-trimethoxybenzene as internal standard.