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(a) Perspective view of the crystal structure of Cd-MOF along the b-axis (blue spheres show the Cd metal). (b) Extended two-dimensional framework structure of Cd-MOF (blue spheres show the Cd metal). (c) Optimized structure of the cadmium MOF at the B3LYP/LANL2DZ level in the gas phase (the atom name with number is given on the spheres; red color for oxygen, yellow color for carbon, blue color for hydrogen, and light blue color for Cd metal).
