Table 3. Preparation of Triazoles 27a–27l by the [3 + 2] Cycloaddition Reactiona.
Reaction conditions: Azide (25–26) (0.25 mmol), 2-(trimethylsilyl)aryl 4-chlorobenzenesulfonate (7a–7e) (0.375 mmol), CsF (0.75 mmol), and 18-crown-6 ether (0.25 mmol) in PhCN (4 mL) were maintained under stirring at 80 °C for 24 h.
Isolated yield.