Table 1.
No. | Tentative Assignement | Rt [min] | UV [nm] | [M-H]− m/z | MS2 Ions m/z |
---|---|---|---|---|---|
CA1 | Unidentified | 3.2 | 226 | 491 | 431, 373 |
CA2 | Unidentified | 4.8 | 217 | 689 | 527, 515, 481, 353, 172 |
CA3 | Hydroxytyrosol glucoside | 5.3 | 290 | 631 * | 315 |
CA4 | Unidentified | 8.5 | 219 | 665 | 491, 373 |
CA5 | Unidentified | 13.6 | 290 | 489 | 314, 173 |
CA6 | Unidentified | 20.6 | 290 | 663 | 616, 521, 489, 405, 329 |
CA7 | Coumaroylquinic acid Tetragalloylglucose |
24.3 24.3 |
290, 310sh overlapped |
337 787 |
191, 163, 119 453, 315 |
CA8 | Quercetin-3-O-(2″-O-galloyl)-hexoside | 33.7 | 270, 360 | 615 | 463, 301 |
CA9 | Quercetin 3-O-rhamnoglucoside | 35.2 | 270, 350 | 609 | 463, 301 |
CA10 | Quercetin 3-O-galactoside | 36.2 | 260, 353 | 463 | 301 |
CA11 | Kaempferol derivative Quercetin hexoside |
37.0 overlapped |
260, 352 | 599 463 |
447, 313, 285, 169 301 |
CA12 | Quercetin 3-O-glucuronide | 38.0 | 255, 352 | 477 | 301 |
CA13 | Kaempferol hexoside | 39.7 | 264, 349 | 447 | 285 |
CA14 | Quercetin (6″-O-malonyl)-3-O-β-d-glucoside | 41.2 | 265, 353 | 549 | 505, 463, 343, 301 |
CA15 | Kaempferol 3-O-glucoside | 41.6 | 264, 344 | 447 | 327, 285 |
CA16 | Kaempferol 3-O-glucuronide | 42.5 | 264, 344 | 461 | 285, 175 |
CA17 | Kaempferol malonyl-hexoside | 44.6 | 264, 344 | 533 | 489, 447, 285 |
CA18 | Kaempferol malonyl-hexoside | 46.4 | 264, 350 | 533 | 489, 285 |
* adduct.