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. 2020 Jan 18;9(1):122. doi: 10.3390/plants9010122

Table 1.

Chromatographic and spectrometric data of compounds identified in Cornus alba fruit extract.

No. Tentative Assignement Rt [min] UV [nm] [M-H] m/z MS2 Ions m/z
CA1 Unidentified 3.2 226 491 431, 373
CA2 Unidentified 4.8 217 689 527, 515, 481, 353, 172
CA3 Hydroxytyrosol glucoside 5.3 290 631 * 315
CA4 Unidentified 8.5 219 665 491, 373
CA5 Unidentified 13.6 290 489 314, 173
CA6 Unidentified 20.6 290 663 616, 521, 489, 405, 329
CA7 Coumaroylquinic acid
Tetragalloylglucose
24.3
24.3
290, 310sh
overlapped
337
787
191, 163, 119
453, 315
CA8 Quercetin-3-O-(2″-O-galloyl)-hexoside 33.7 270, 360 615 463, 301
CA9 Quercetin 3-O-rhamnoglucoside 35.2 270, 350 609 463, 301
CA10 Quercetin 3-O-galactoside 36.2 260, 353 463 301
CA11 Kaempferol derivative
Quercetin hexoside
37.0
overlapped
260, 352 599
463
447, 313, 285, 169
301
CA12 Quercetin 3-O-glucuronide 38.0 255, 352 477 301
CA13 Kaempferol hexoside 39.7 264, 349 447 285
CA14 Quercetin (6″-O-malonyl)-3-O-β-d-glucoside 41.2 265, 353 549 505, 463, 343, 301
CA15 Kaempferol 3-O-glucoside 41.6 264, 344 447 327, 285
CA16 Kaempferol 3-O-glucuronide 42.5 264, 344 461 285, 175
CA17 Kaempferol malonyl-hexoside 44.6 264, 344 533 489, 447, 285
CA18 Kaempferol malonyl-hexoside 46.4 264, 350 533 489, 285

* adduct.