Table 5.
Chemical compositions of Callicarpa longifolia leaf essential oils from Vietnam.
| RI a | RI b | Compound | % | |
|---|---|---|---|---|
| Da Nang | Nghia Dan | |||
| 931 | 932 | α-Pinene | 0.4 | 0.1 |
| 1007 | 1008 | δ-3-Carene | --- | tr c |
| 1022 | 1024 | p-Cymene | --- | tr |
| 1028 | 1024 | Limonene | 0.5 | 0.1 |
| 1033 | 1032 | (Z)-β-Ocimene | --- | tr |
| 1043 | 1044 | (E)-β-Ocimene | --- | tr |
| 1097 | 1095 | Linalool | --- | 1.0 |
| 1101 | 1104 | Hotrienol | --- | tr |
| 1103 | 1100 | Nonanal | --- | tr |
| 1105 | 1110 | Octen-3-yl acetate | --- | tr |
| 1110 | 1113 | 4,8-Dimethylnona-1,3,7-triene | --- | tr |
| 1116 | 1118 | 3-Octyl acetate | --- | tr |
| 1190 | 1190 | Methyl salicylate | --- | 0.9 |
| 1192 | 1197 | (2E)-Hexenyl butyrate | --- | tr |
| 1193 | 1186 | α-Terpineol | --- | 0.1 |
| 1221 | 1227 | Nerol | --- | tr |
| 1234 | 1226 | (2E)-Hexenyl 2-methylbutyrate | --- | tr |
| 1247 | 1249 | Geraniol | --- | 0.1 |
| 1290 | 1287 | Dihydroedulan IIA | --- | 0.1 |
| 1295 | 1294 | (Z)-Theaspirane | --- | 0.2 |
| 1311 | 1298 | (E)-Theaspirane | --- | 0.2 |
| 1330 | 1334 | Bicycloelemene | 0.2 | 0.4 |
| 1333 | 1335 | δ-Elemene | 0.1 | 2.7 |
| 1349 | 1352 | Tricyclosantalal A | --- | 0.2 |
| 1374 | 1374 | α-Copaene | 0.4 | 0.6 |
| 1375 | 1383 | (E)-β-Damascenone | --- | 0.2 |
| 1387 | 1389 | β-Elemene | 0.5 | 0.4 |
| 1401 | 1408 | (Z)-Caryophyllene | --- | 0.1 |
| 1403 | 1409 | α-Gurjunene | --- | 0.2 |
| 1407 | 1415 | β-Maaliene | 0.7 | --- |
| 1409 | 1411 | cis-α-Bergamotene | --- | 0.1 |
| 1418 | 1417 | (E)-Caryophyllene | 11.8 | 28.0 |
| 1427 | 1434 | γ-Elemene | 0.6 | 1.3 |
| 1429 | 1432 | trans-α-Bergamotene | --- | 0.5 |
| 1431 | 1438 | α-Maaliene | --- | 0.1 |
| 1436 | 1439 | Aromadendrene | 0.2 | 0.5 |
| 1438 | 1442 | 6,9-Guaiadiene | --- | 0.5 |
| 1447 | 1445 | Myltayl-4(12)-ene | 0.7 | --- |
| 1449 | 1457 | Sesquisabinene | --- | 0.3 |
| 1452 | 1454 | (E)-β-Farnesene | 1.6 | --- |
| 1454 | 1452 | α-Humulene | 1.9 | 1.6 |
| 1458 | 1458 | allo-Aromadendrene | 1.4 | 0.8 |
| 1472 | 1478 | γ-Muurolene | --- | 0.2 |
| 1473 | 1475 | γ-Gurjunene | --- | 0.6 |
| 1479 | 1484 | Germacrene D | 0.3 | 0.2 |
| 1483 | 1488 | δ-Selinene | --- | 0.7 |
| 1484 | 1476 | β-Chamigrene | 4.0 | --- |
| 1488 | 1489 | β-Selinene | 3.2 | 13.2 |
| 1489 | 1491 | Eremophilene | 4.3 | --- |
| 1492 | 1500 | Bicyclogermacrene | --- | 5.9 |
| 1494 | 1496 | Valencene | 1.4 | --- |
| 1494 | 1500 | α-Muurolene | --- | 0.2 |
| 1500 | 1502 | trans-β-Guaiene | 22.2 | 0.4 |
| 1510 | 1505 | β-Bisabolene | 1.2 | 0.3 |
| 1504 | 1507 | Eremophila-1(10),8,11-triene | 0.3 | --- |
| 1511 | 1513 | γ-Cadinene | 0.2 | 0.2 |
| 1510 | 1508 | 6-epi-Shyobunone | 0.3 | --- |
| 1516 | 1522 | δ-Cadinene | 0.4 | 0.2 |
| 1520 | 1520 | 7-epi-α-Selinene | 3.5 | --- |
| 1535 | 1540 | Selina-4(15),7(11)-diene | 0.2 | 0.3 |
| 1538 | 1544 | α-Calacorene | --- | 0.2 |
| 1557 | 1559 | Germacrene B | 1.3 | 2.1 |
| 1557 | 1561 | (E)-Nerolidol | --- | 0.1 |
| 1570 | 1567 | Palustrol | 0.9 | --- |
| 1576 | 1577 | Spathulenol | 1.1 | 5.3 |
| 1581 | 1582 | Caryophyllene oxide | 1.7 | 6.1 |
| 1584 | 1590 | Globulol | 0.2 | 0.2 |
| 1593 | 1592 | Viridiflorol | 0.3 | 0.2 |
| 1598 | 1596 | trans-β-Elemenone | 0.6 | --- |
| 1605 | 1602 | Ledol | 2.4 | --- |
| 1606 | --- | Unidentified d | 2.5 | --- |
| 1610 | 1608 | Humulene epoxide II | 0.3 | --- |
| 1616 | --- | Unidentified e | 0.2 | 2.7 |
| 1623 | 1624 | Selina-6-en-4β-ol | --- | 0.4 |
| 1627 | 1629 | iso-Spathulenol | 0.2 | 4.2 |
| 1629 | 1642 | Caryophylla-4(12),8(13)-dien-5α-ol | --- | 0.6 |
| 1632 | 1637 | Dehydroxycalamendiol | 0.7 | --- |
| 1634 | 1644 | Caryophylla-4(12),8(13)-dien-5β-ol | --- | 0.2 |
| 1652 | 1649 | β-Eudesmol | --- | 0.9 |
| 1655 | 1652 | α-Cadinol | 0.7 | --- |
| 1662 | 1658 | Selin-11-en-4α-ol | 8.0 | 7.4 |
| 1668 | --- | Unidentified f | 1.4 | --- |
| 1670 | --- | Unidentified g | 1.2 | --- |
| 1679 | 1685 | Germacra-4(15),5,10(14)-trien-1α-ol | --- | 0.4 |
| 1685 | 1685 | α-Bisabolol | 0.8 | --- |
| 1686 | 1690 | (Z)-trans-α-Bergamotol | --- | 0.5 |
| 1693 | 1693 | Germacrone | 2.7 | --- |
| 1704 | 1706 | (E)-trans-α-Bergamotol | --- | 0.3 |
| 1711 | 1715 | Pentadecanal | --- | 0.3 |
| 1723 | 1729 | Isobicyclogermacrenal | 0.7 | --- |
| 1738 | 1734 | 1(10),11-Eremophiladien-9-one | 6.7 | --- |
| 1747 | 1744 | Isocalamenediol | 0.5 | --- |
| 1765 | 1766 | β-Costol | --- | 0.4 |
| 1768 | 1773 | α-Costol | --- | 0.4 |
| 1777 | 1786 | trans-Isovalencenol | 0.2 | --- |
| 1886 | 1891 | (E)-Hexadecantrienal | --- | 0.2 |
| 2045 | 2046 | Kaur-16-ene | 0.3 | --- |
| 2101 | 2109 | (E)-Phytol | --- | 0.5 |
| Monoterpene hydrocarbons | 0.9 | 0.1 | ||
| Oxygenated monoterpenoids | 0.0 | 1.2 | ||
| Sesquiterpene hydrocarbons | 63.0 | 62.9 | ||
| Oxygenated sesquiterpenoids | 29.4 | 27.8 | ||
| Diterpenoids | 0.3 | 0.5 | ||
| Others | 0.0 | 2.3 | ||
| Total identified | 93.5 | 94.8 | ||
a RI = Retention Index determined with respect to a homologous series of n-alkanes on a ZB-5 column. b Retention indices from the databases. c tr = trace (<0.05%). d MS: 220(10%), 205(20%), 178(21%), 177 (47%), 153(19%), 140(30%), 135(20%), 121(17%), 107(47%), 97(100%), 93(44%), 81(73%), 79(65%), 69(57%), 67(31%), 55(56%), 41(53%). e MS: 222(3%), 207(38%), 204(42%), 189(40%), 161(33%), 147(25%), 137(27%), 135(55%), 133(25%), 121(28%), 109(42%), 107(35%), 105(26%), 95(47%), 93(41%), 81(94%), 71(54%), 67(41%), 55(41%), 43(100%), 41(39%). f MS: 220(16%), 205(96%), 202(20%), 187(35%), 177(35%), 163(40%), 159(100%), 151(50%), 149(40%), 145(57%), 131(52%), 121(59%), 119(88%), 109(55%), 107(81%), 105(85%), 93(98%), 91(90%), 79(70%), 67(69%), 55(73%), 41(73%). g MS: 220(3%), 205(64%), 189(33%), 177(21%), 162(29%), 147(100%), 138(40%), 133(66%), 119(45%), 109(44%), 107(50%), 105(64%), 93(73%), 91(79%), 79(71%), 67(54%), 55(60%), 41(57%).