Table 8.
Chemical compositions of Callicarpa rubella leaf essential oils from Vietnam.
| RI a | RI b | Compound | % | ||
|---|---|---|---|---|---|
| Nam Giai | Bach Ma | Tay Giang | |||
| 923 | 924 | α-Thujene | --- | 0.1 | tr c |
| 930 | 932 | α-Pinene | 0.1 | 0.5 | 1.1 |
| 946 | 946 | Camphene | --- | --- | tr |
| 971 | 969 | Sabinene | --- | 0.1 | 0.1 |
| 975 | 974 | β-Pinene | 0.3 | 2.4 | 1.7 |
| 977 | 974 | 1-Octen-3-ol | 0.4 | 0.1 | tr |
| 982 | 979 | 3-Octanone | 0.2 | --- | tr |
| 986 | 988 | Myrcene | --- | 0.1 | 0.2 |
| 987 | 984 | 2-Pentylfuran | --- | --- | tr |
| 995 | 988 | 3-Octanol | 0.4 | 0.1 | tr |
| 1005 | 1002 | α-Phellandrene | --- | 0.3 | 3.0 |
| 1007 | 1008 | δ-3-Carene | --- | 0.3 | tr |
| 1015 | 1014 | α-Terpinene | --- | --- | tr |
| 1022 | 1024 | p-Cymene | tr | 0.7 | 1.0 |
| 1027 | 1024 | Limonene | 0.1 | 0.4 | 0.8 |
| 1028 | 1025 | β-Phellandrene | --- | 0.9 | 2.6 |
| 1030 | 1026 | 1,8-cineole | --- | 0.1 | --- |
| 1033 | 1032 | (Z)-β-Ocimene | --- | --- | 0.1 |
| 1043 | 1044 | (E)-β-Ocimene | --- | --- | tr |
| 1055 | 1054 | γ-Terpinene | --- | --- | tr |
| 1067 | 1067 | cis-Linalool oxide (furanoid) | 0.2 | --- | --- |
| 1083 | 1086 | Terpinolene | --- | 0.1 | 0.1 |
| 1084 | 1084 | trans-Linalool oxide (furanoid) | 0.2 | --- | --- |
| 1098 | 1095 | Linalool | 1.4 | 0.1 | tr |
| 1104 | 1100 | Nonanal | --- | 0.1 | tr |
| 1123 | 1118 | cis-p-Menth-2-en-1-ol | --- | tr | --- |
| 1137 | 1134 | Benzeneacetonitrile | 0.1 | --- | --- |
| 1139 | 1135 | trans-Pinocarveol | 0.1 | tr | --- |
| 1141 | 1136 | trans-p-Menth-2-en-1-ol | --- | tr | --- |
| 1161 | 1160 | Pinocarvone | --- | tr | --- |
| 1170 | 1165 | Borneol | --- | tr | --- |
| 1179 | 1174 | Terpinen-4-ol | --- | 0.1 | tr |
| 1185 | 1183 | Cryptone | --- | 0.2 | --- |
| 1185 | 1184 | (3Z)-Hexenyl butyrate | 0.2 | --- | --- |
| 1189 | 1191 | Hexyl butyrate | tr | --- | --- |
| 1191 | 1190 | Methyl salicylate | 0.2 | --- | tr |
| 1192 | 1193 | (2E)-Hexenyl butyrate | 0.1 | --- | --- |
| 1193 | 1195 | Myrtenal | 0.1 | --- | --- |
| 1194 | 1186 | α-Terpineol | --- | 0.3 | 0.1 |
| 1201 | 1202 | cis-Sabinol | --- | 0.1 | --- |
| 1221 | 1222 | 2-Hydroxycineole | --- | 0.1 | --- |
| 1285 | 1287 | Dihydroedulan IA | 0.1 | --- | tr |
| 1290 | 1294 | Dihydroedulan IIA | 0.1 | --- | tr |
| 1295 | 1299 | (Z)-Theaspirane | --- | --- | 0.1 |
| 1312 | 1303 | (E)-Theaspirane | --- | --- | tr |
| 1318 | 1318 | 3-Hydroxycineole | --- | 0.3 | --- |
| 1328 | 1334 | Bicycloelemene | --- | 0.2 | 0.3 |
| 1332 | 1335 | δ-Elemene | --- | 0.2 | 0.2 |
| 1344 | 1345 | α-Cubebene | 0.1 | 0.4 | 17.4 |
| 1350 | 1356 | Eugenol | --- | --- | 0.1 |
| 1366 | 1373 | α-Ylangene | 0.1 | --- | tr |
| 1372 | 1374 | α-Copaene | 0.4 | 0.1 | 4.6 |
| 1377 | 1383 | (E)-β-Damascenone | --- | --- | tr |
| 1380 | 1382 | β-Bourbonene | 3.2 | 0.1 | 4.1 |
| 1383 | 1385 | α-Bourbonene | 0.3 | --- | --- |
| 1384 | 1387 | β-Cubebene | --- | --- | 4.3 |
| 1386 | 1389 | β-Elemene | 0.5 | 1.3 | 0.5 |
| 1400 | 1408 | (Z)-Caryophyllene | --- | --- | 0.1 |
| 1403 | 1409 | α-Gurjunene | --- | --- | 0.1 |
| 1414 | 1419 | β-Ylangene | 0.3 | --- | --- |
| 1417 | 1417 | (E)-Caryophyllene | 0.3 | 7.1 | 18.0 |
| 1426 | 1430 | β-Copaene | 0.3 | --- | 0.7 |
| 1426 | 1427 | γ-Elemene | --- | 2.5 | --- |
| 1430 | 1432 | trans-α-Bergamotene | --- | 0.1 | --- |
| 1431 | 1437 | α-Guaiene | 2.8 | --- | 3.0 |
| 1435 | 1439 | Aromadendrene | 0.1 | --- | 0.3 |
| 1441 | 1447 | iso-Germacrene D | 0.2 | --- | 0.3 |
| 1445 | 1448 | cis-Murrola-3,5-diene | --- | --- | 0.6 |
| 1449 | 1454 | (E)-β-Farnesene | --- | 0.5 | 0.1 |
| 1452 | 1452 | α-Humulene | 0.1 | 0.9 | 2.0 |
| 1456 | 1458 | allo-Aromadendrene | --- | --- | 0.2 |
| 1459 | 1465 | cis-Muurola-4(14),5-diene | --- | --- | 0.1 |
| 1465 | 1461 | cis-Cadina-1(6),4-diene | --- | --- | 0.2 |
| 1466 | 1473 | Drima-7,9(11)-diene | 0.1 | --- | --- |
| 1468 | 1475 | trans-Cadina-1(6),4-diene | --- | --- | 0.8 |
| 1471 | 1478 | γ-Muurolene | 0.5 | --- | 0.5 |
| 1476 | 1475 | γ-Gurjunene | 0.2 | --- | 0.4 |
| 1478 | 1479 | ar-Curcumene | --- | 0.7 | --- |
| 1478 | 1484 | Germacrene D | --- | --- | 4.2 |
| 1486 | 1489 | β-Selinene | 1.6 | 0.9 | 0.8 |
| 1488 | 1495 | γ-Amorphene | --- | --- | 1.2 |
| 1492 | 1500 | Bicyclogermacrene | --- | --- | 4.6 |
| 1493 | 1498 | α-Selinene | --- | 0.7 | --- |
| 1495 | 1500 | α-Muurolene | --- | 0.1 | 0.9 |
| 1495 | --- | Unidentified d | 2.7 | --- | --- |
| 1498 | 1509 | α-Bulnesene | 1.7 | --- | 1.8 |
| 1500 | 1505 | (E,E)-α-Farnesene | --- | --- | 0.1 |
| 1505 | 1505 | β-Bisabolene | 0.7 | 25.0 | 0.1 |
| 1510 | 1513 | γ-Cadinene | --- | 0.1 | 0.3 |
| 1512 | 1514 | Cubebol | --- | 0.5 | 1.0 |
| 1515 | 1518 | δ-Cadinene | --- | 0.2 | 4.6 |
| 1519 | 1521 | trans-Calamenene | --- | 0.2 | 0.4 |
| 1520 | 1528 | Zonarene | --- | --- | 0.2 |
| 1521 | 1521 | β-Sesquiphellandrene | --- | 0.5 | --- |
| 1529 | 1533 | trans-Cadina-1,4-diene | --- | --- | 0.4 |
| 1534 | 1540 | Selina-4(15),7(11)-diene | --- | 0.5 | --- |
| 1539 | 1545 | Selina-3,7(11)-diene | --- | 0.3 | --- |
| 1545 | 1548 | α-Elemol | --- | 0.2 | --- |
| 1556 | 1559 | Germacrene B | --- | 4.6 | 0.1 |
| 1564 | --- | Unidentified e | 3.2 | --- | --- |
| 1568 | --- | Unidentified f | 7.2 | --- | --- |
| 1574 | 1577 | Spathulenol | 3.9 | 0.2 | 2.7 |
| 1579 | 1582 | Caryophyllene oxide | 25.1 | 3.0 | 2.7 |
| 1581 | --- | Unidentified g | 1.7 | --- | 0.3 |
| 1590 | 1590 | cis-β-Elemenone | --- | 0.4 | --- |
| 1595 | 1596 | trans-β-Elemenone | --- | 4.2 | --- |
| 1607 | 1608 | Humulene epoxide II | 3.8 | 0.4 | 0.2 |
| 1625 | 1629 | iso-Spathulenol | --- | 0.6 | --- |
| 1625 | 1627 | 1-epi-Cubenol | --- | --- | 0.8 |
| 1634 | 1644 | Caryophylla-4(12),8(13)-dien-5β-ol | --- | --- | 0.2 |
| 1640 | 1645 | Cubenol | --- | --- | 0.5 |
| 1641 | 1640 | τ-Muurolol | --- | --- | 0.1 |
| 1644 | 1644 | α-Muurolol (= δ-Cadinol) | --- | --- | 0.3 |
| 1653 | 1652 | α-Cadinol | --- | 0.4 | 0.2 |
| 1655 | 1651 | Pogostol | 1.6 | --- | 0.2 |
| 1661 | --- | Unidentified h | --- | 2.2 | --- |
| 1668 | 1668 | 14-Hydroxy-9-epi-(E)-caryophyllene | 1.2 | --- | 0.1 |
| 1677 | --- | Unidentified i | 1.1 | --- | --- |
| 1684 | 1685 | α-Bisabolol | --- | 0.2 | --- |
| 1691 | 1693 | Germacrone | --- | 22.1 | --- |
| 1698 | 1704 | cis-Thujopsenol | 8.8 | --- | --- |
| 1709 | --- | Unidentified j | --- | 1.8 | --- |
| 1715 | --- | Unidentified k | 2.1 | --- | --- |
| 1766 | --- | Unidentified l | 1.8 | --- | --- |
| 1768 | --- | Unidentified m | --- | 1.0 | --- |
| 1792 | --- | Unidentified n | 4.0 | --- | --- |
| 1802 | --- | Unidentified o | 2.5 | --- | --- |
| 1809 | 1806 | Nootkatone | 1.6 | --- | --- |
| 1815 | --- | Unidentified p | --- | 1.8 | --- |
| 1834 | --- | Unidentified q | --- | 3.0 | --- |
| 1849 | --- | Unidentified r | 1.6 | --- | --- |
| 1885 | 1884 | Corymbolone | 5.6 | --- | --- |
| 2049 | 2055 | Abietatriene | --- | 1.3 | 0.1 |
| Monoterpene hydrocarbons | 0.5 | 5.9 | 10.5 | ||
| Oxygenated monoterpenoids | 2.0 | 1.2 | 0.1 | ||
| Sesquiterpene hydrocarbons | 13.5 | 47.1 | 78.5 | ||
| Oxygenated sesquiterpenoids | 45.9 | 32.3 | 9.0 | ||
| Diterpenoids | 5.6 | 1.3 | 0.1 | ||
| Others | 1.8 | 0.2 | 0.1 | ||
| Total identified | 69.2 | 88.0 | 98.3 | ||
a RI = Retention Index determined with respect to a homologous series of n-alkanes on a ZB-5 column. b Retention indices from the databases. c tr = trace (<0.05%). d MS: 202(24%), 189(12%), 187(14%), 159(28%), 147(66%), 145(53%), 134(30%), 133(31%), 131(35%), 121(37%), 119(59%), 107(68%), 105(99%), 93(92%), 91(79%), 81(100%), 80(69%), 79(74%), 77(42%), 67(35%), 55(40%), 41(55%). e MS: 220(3%), 205(13%), 187(18%), 162(34%), 147(27%), 145(30%), 135(35%), 121(67%), 107(85%), 95(74%), 93(77%), 81(81%), 79(67%), 69(68%), 67(82%), 55(87%)41(100%). f MS: 220(0.5%), 205(4%), 187(12%), 177(6%), 162(9%), 149(9%), 147(20%), 145(13%), 123(26%), 122(24%), 111(44%), 107(78%), 95(42%), 93(42%), 83(40%), 81(58%), 79(38%), 67(47%), 55(43%), 43(100%), 41(49%). g MS: 220(3%), 205(4%), 202(12%), 187(24%), 159(25%), 146(29%), 145(23%), 133(22%), 131(20%), 123(18%), 121(19%0, 119(18%), 109(18%), 107(27%), 105(28%), 95(29%), 93(35%), 91(30%), 81(35%), 79(36%), 69(27%), 55(32%), 43(100%), 41(33%). h MS: 218(4%), 203(5%), 175(14%), 136(68%), 135(68%), 121(25%), 107(100%), 91(29%), 79(22%), 67(50%), 53(18%), 41(28%). i MS: 218(7%), 203(8%), 175(12%), 161(17%), 160(18%), 147(22%), 145(15%), 135(28%), 134(29%), 121(32%), 119(33%), 109(42%), 107(35%), 105(33%), 95(59%), 93(41%), 81(34%), 79(30%), 69(30%), 67(37%),55(29%), 53(19%), 43(100%), 41(43%). j MS: 220(35%), 205(17%), 202(27%), 187(27%), 162(88%), 159(32%), 149(55%), 147(57%), 145(30%), 131(30%), 121(71%), 119(79%), 107(66%), 105(68%), 97(43%), 93(57%), 91(67%), 43(100%), 41(63%). k MS: 218(2%), 200(3%), 185(5%), 160(13%), 145(9%), 121(25%), 120(27%), 98(22%), 97(23%), 83(100%), 67(18%), 55(34%), 43(96%), 41(25%). l MS: 220(1%), 205(4%), 179(10%), 161(4%), 147(10%), 137(10%), 133(14%), 121(17%), 119(20%), 108(32%), 95(35%), 93(53%), 91(42%), 81(34%), 79(61%), 69(32%), 67(38%), 55(45%), 43(100%), 41(58%). m MS: 220(62%), 202(11%), 187(15%), 177(100%), 159(74%), 135(49%), 123(75%), 107(76%), 93(64%), 91(52%), 81(61%), 67(54%), 55(57%), 43(62%), 41(68%). n MS: 234(8%), 219(30%), 216(8%), 201(8%), 191(12%), 177(15%), 176(13%), 163(14%), 159(16%), 152(21%), 137(16%), 133(16%), 111(27%), 105(20%), 91(25%), 79(19%), 77(17%), 67(17%), 55(17%), 43(100%), 41(26%). o MS: 234(1%), 216(16%), 188(8%), 177(9%), 173(8%), 163(10%), 161(14%), 159(13%), 133(22%), 111(26%), 105(24%), 95(47%), 91(23%), 81(23%), 79(24%), 77(20%), 67(22%), 55(18%), 43(100%), 41(28%). p MS: 234(2%), 219(4%), 201(5%), 191(5%), 177(7%), 167(12%), 149(34%), 135(51%), 121(50%), 107(100%), 93(35%), 91(37%), 79(34%), 68(36%), 67(58%), 55(34%), 43(53%), 41(60%). q MS: 167(40%), 121(32%), 68(100%), 67(58%), 43(33%), 41(39%). r MS: 236(5%), 221(8%), 218(8%), 193(15%), 180(26%), 167(30%), 149(22%), 147(18%), 136(65%), 123(74%), 110(97%), 97(84%), 69(83%), 55(80%), 43(80%), 41(100%).