Scheme 2. Representative examples of aminations under sustainable aqueous micellar conditions. Unless otherwise mentioned: X = Br, [LPd] = 1000 ppm [t-BuXPhosPd(cinnamyl)]OTf, temp = 45 °C, time = 16 h; KO-t-Bu or K3PO4·H2O used as inorganic base in 2 wt% TPGS-750-M at 0.5 M global concentration (see ESI† for additional details). *Product isolated by simple filtration.
