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Structure and properties of black phosphorus (BP) crystals grown by the mineralization method: (a) photograph of a 1.5 cm BP single crystal; (b) SEM image and (c) low-magnification and (d) high-resolution TEM images of the BP crystal; and (e) selected area electron diffraction (SAED) pattern, (f) EDS spectrum, and (g) XRD pattern of the BP single crystal.
