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. 2019 Dec 20;12(1):17. doi: 10.3390/polym12010017

Table 2.

Primary nucleation and growth isothermal kinetics data parameters according to Equations (1) and (3) derived from experimental results obtained by PLOM.

Copolyester Nucleation, Equation (1) Growth, Equation (3)
Δσ (erg/cm2) aR 2 KgG (K2) σ (erg/cm2) σe (erg/cm2) q (erg) bR 2
PBS 1.97 0.938 8.66 × 104 12.4 79.5 3.37 × 10−13 0.983
BS91CL9  1.55 0.963 5.80 × 104 12.4 55.0 2.33 × 10−13 0.994
BS78CL22  1.52 0.993 5.12 × 104 12.4 49.6 2.10 × 10−13 0.973
BS66CL34  0.58 0.977 8.94 × 104 12.4 88.9 3.78 × 10−13 0.982
BS62CL38  0.36 0.913 8.92 × 104 12.4 89.4 3.87 × 10−13 0.982
BS55CL45  0.44 0.920 14.4 × 104 12.4 148.8 6.30 × 10−13 0.999
BS51CL49  0.32 0.944 14.5 × 104 12.4 148.9 6.32 × 10−13 0.999
BS45CL55  0.14 0.973 15.7 × 104 12.4 165.5 7.02 × 10−13 0.974
BS11CL89  1.13 0.867 14.7 × 104 6.8 169.6 6.32 × 10−13 0.999
PCL 1.53 0.999 10.4 × 104 6.8 112.0 4.17 × 10−13 0.996

a R2 is the correlation coefficient for the fitting of the nucleation kinetics with the Turnbull–Fisher model (Equation (1)), log I vs. 1/TT)2. b R2 is the correlation coefficient for the fitting of the Lauritzen–Hoffman model (Equation (3)), lnG + U*/R(TcT0) vs. 1/f.Tc.ΔT.