Table 1.
Apparent pKa values determined for 1–5 and their [Ru(η6-C6H5CH2CH2NHR)(C2O4)(H2O)] analogues.
| Complex | Apparent pKa | Apparent pKa for the Analogous [Ru(η6-C6H5CH2CH2NHR)(C2O4)(H2O)] Complex |
|---|---|---|
| 1 | 7.32 | 6.65 ‡ |
| 2 | 6.41 | 5.75 |
| 3 | 4.50 | 4.05 ‡ |
| 4 | 4.82 | - |
| 5 | 8.00 | - |
‡ Values for [Ru(η6-C6H5CH2CH2NHR)(C2O4)(H2O)] (R = Ms, Tf) have been reported previously [15].