Table 1.
No. | Compound | λmax [nm] | m/z [M + H]+ | m/z from MS/MS of [M + H]+ |
---|---|---|---|---|
1 | betanin | 538 | 551 | 389 |
1a | 18-chloro-betanin | 522 | 585 | 423 |
2 | 17-decarboxy-betanin | 505 | 507 | 345 |
2a | 18-chloro-17-decarboxy-betanin | 524 | 541 | 379 |
3 | 15-decarboxy-betanin | 528 | 507 | 345 |
3a | 18-chloro-15-decarboxy-betanin | 514 | 541 | 379 |
4 | 2-decarboxy-betanin | 533 | 507 | 345 |
4a | 18-chloro-2-decarboxy-betanin | 525 | 541 | 379 |
5 | betanidin | 540 | 389 | 345 |
5a | 18-chloro-betanidin | 528 | 423 | 377 |
6/6’ | 2,17-bidecarboxy-betanin/-isobetanin | 507 | 463 | 301 |
6a | 18-chloro-2,17-bidecarboxy-betanin | 519 | 497 | 335 |
7 | neobetanin | 466 | 549 | 387; 343; 299 |