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. Author manuscript; available in PMC: 2020 Apr 10.

Published in final edited form as: J Am Chem Soc. 2019 Mar 27;141(14):6022–6029. doi: 10.1021/jacs.9b01387

Table 1.

Selected Bond Lengths and Angles for Compounds 1–5

	bond length (Å)						bond angle (deg)
compd	Cr–O1	Cr–O2	Cr–O3	Cr–C1	Cr–C2	Cr–C3	O1–Cr–C1	O2–Cr–C2	O3–Cr–C3
1	2.152(2)	2.176(2)	2.139(2)	2.038(2)	2.040(3)	2.039(3)	79.69(9)	79.81(9)	79.68(9)
2	2.1529(8)	2.1893(7)	n/a^a	2.050(1)	2.037(1)	2.067(1)	86.41(4)	90.67(3)	n/a^a
3	2.230(2)	2.293(2)	2.138(1)	2.032(2)	2.034(2)	2.040(2)	64.81(7)	63.63(7)	93.41(7)^b
4	2.2059(9)	2.1963(8)	2.1844(8)	2.104(1)	2.081(1)	2.079(1)	88.75(4)	88.05(4)	88.32(4)
5	2.181(1)	2.108(1)	n/a^a	2.056(2)	2.072(2)	n/a^a	90.39(6)	88.02(6)	n/a^a

^a

Not applicable.

^b

O3 in compound 3 is part of the bridging arylether ligand.