Table 2.

A list of representative hydrophobic MOFs reported in the literature

MOF	Formula	Ligand a)	S BET/S L b) [m2 g−1]	V p c) [cm3 g−1]	d a d) [Å]	d p e) [Å]	$C_{{\text{H}}_2\text{O}}$ f) [mg g−1]	α g) (P/P 0)	CA h) [°]	Ref.
[Cd(O2C‐CH2‐CO2)(H2O)]	[Cd(ma)(H2O)]	H2ma			6.95					100
[Mn(O2C‐(CH2)3‐CO2)]	[Mn(glu)]	H2glu			6.6					100
CPM‐300	[Zn4O(RR‐cam)3]	RR‐H2cam	310.5/ 429.9		8				138.7	101
CPM‐301	[Zn4O(RRcam)3][Zn9(btz)12(RR‐cam)3]	RR‐H2cam, Hbtz							145.0	101
MIL‐140A	[ZrO(1,4‐bdc)]	1,4‐H2bdc	415/–	0.18	3.2		– i)	0.5		71
MIL‐101(Cr)	[Cr3O(H2O)2F(1,4‐bdc)3]	1,4‐H2bdc	3124/–	1.58	12, 16 × 14.5	29, 34	1360	0.48		102
MIL‐101‐NO2	[Cr3O(H2O)2F(1,4‐bdc‐2‐NO2)3]	1,4‐H2bdc‐2‐NO2	2146/–	1.19			1060	0.47		102
MIL‐68(In)	[In(OH)(1,4‐bdc)]	1,4‐H2bdc	1100/–	0.42	6.0–6.4; 16–17		320	0.58		103
Banasorb‐22	[(Zn4O)(1,4‐bdc‐2‐CF3O)3]	1,4‐H2bdc‐2‐CF3O	1113/–				80			72
UiO‐66	[Zr6O4(OH)4(1,4‐bdc)6]	1,4‐H2bdc	1105/–	0.55	7	8–11	453	0.27		104
UiO‐66−1,4‐Naphyl	[Zr6O4(OH)4(1,4‐ndc)6]	1,4‐H2ndc	757/–	0.42			297	0.31		104
UiO‐66‐(C2H5)2	[Zr6O4(OH)4(1,4‐bdc‐(C2H5)2)6]	1,4‐H2bdc‐(C2H5)2	340/–	0.16			122	0.5		87
UiO‐66‐C2F5	[Zr6O4(OH)4(1,4‐bdc‐C2F5)6]	1,4‐H2bdc‐C2F5	570/–	0.26			252	0.6		87
UiO‐66‐(CF3)2	[Zr6O4(OH)4(1,4‐bdc‐(CF3)2)6]	1,4‐H2bdc‐(CF3)2	630/–	0.30			190	0.35		87
UiO‐66‐CH3	[Zr6O4(OH)4(1,4‐bdc‐CH3)6]	1,4‐H2bdc‐CH3	760/–	0.32			253	0.22		87
UiO‐66‐(CH3)2	[Zr6O4(OH)4(1,4‐bdc‐(CH3)2)6]	1,4‐H2bdc‐(CH3)2	790/–	0.35			279	0.38		87
UiO‐66‐CF3	[Zr6O4(OH)4(1,4‐bdc‐CF3)6]	1,4‐H2bdc‐CF3	815/–	0.36			279	0.32		87
MIL‐140B	[ZrO(2,6‐ndc)]	2,6‐H2ndc	460/–	0.18	4.0		%	0.5		71
MIL(Cr)‐Z1	[Cr3O(H2O)2F(1,4‐ndc)3]	1,4‐H2ndc	2086/–	1.23	6.9	23.3	318.6	0.64		105
Al(OH)(1,4‐ndc)	[Al(OH)(1,4‐ndc)]	1,4‐H2ndc	–/546		3.0–7.7		165	0.47		106
[Cu(1,4‐ndc)(MeOH)]	[Cu(1,4‐ndc)(MeOH)]	1,4‐H2ndc	–/133.7		≈3.8		22	0.4		107
UiO‐67‐BN	[Zr6O4(OH)4(bn)6]	H2bn	1416/–				495	0.54		108
UiO‐67‐4MS	[Zr6O4(OH)4(tmbpd)6]	H2tmbpd	1153/–					82		109
UiO‐66D‐(CF3)2	[Zr6O4(OH)4(abdc‐(CF3)2)6]	H2abdc‐(CF3)2	2180/–	0.88			281	0.87		87
NMOF‐1	[Zn(ope‐C18)(H2O)2]	H2ope‐C18			≈3.3		16	≈0.45	160–162	110
IFMC‐29	[Zn4O(CH3PhTDC)3]	H2CH3PhTDC	1892/–	0.64					93	111
MOFF‐1	[Cu(bpdc‐F8)(MeOH)]	H2bpdc‐F8	580/–				136	0.45	108	112
Zn(tbip)	[Zn(tbip)]	H2tbip	256/–	0.15	4.5		110	0.56		113
Zn‐hfipbb	[Zn(hfipbb)]	H2hfipbb	287/288.9	0.112	6.7		≈0			114, 115
[Cu(hfipbb)(H2hfipbb)0.5]	[Cu(hfipbb)(H2hfipbb)0.5]	H2hfipbb		0.07	3.5	5.1				116, 117
Fe‐hfipbb	[Fe3O(hfipbb)3]	H2hfipbb	269.5/–	0.21	8–12.9				110	118
MAMS‐2	[Zn(H2O)(bbpdc)]	H2bbpdc			2.9–4.6					119
UHMOF‐100	[Cu(tpda)(DMF)]	H2tpda	660/469	1.07	5.9		≈0		177	120
BUT‐66	[Zr6O4(OH)4(1,3‐bdb)6]	1,3‐H2bdb	1096/1291	0.46	6.0		71	0.4	142.8	88
BUT‐67	[Zr6O4(OH)4(2,7‐ndb)6]	2,7‐H2ndb	984/1141	0.41	7		124	0.45	137.9	88
CuMBTC	[Cu3(mbtc)2]	H3mbtc	1471/–	0.78	8.8–12.7		184	0.2		121
CuEBTC	[Cu3(ebtc)2]	H3ebtc	1434/–	0.65	7.8–12.2		184	0.1		121
BUT‐12	[Zr6O4(OH)8(H2O)4(ctta)8/3]	H3ctta	3387/–	1.52	13–21		434	0.4	138.7	122
BUT‐13	[Zr6O4(OH)8(H2O)4(ttna)8/3]	H3ttna	3948/–	2.20	14–28		494	0.52	118.3	122
PESD‐1	[Zn4(OH)2(btmb)2(DMF)3(MeOH)]	H3btmb	295/570						>150	123
[Pb(H‐BTMB)]	[Pb(Hbtmb)(DMF)]	H3btmb	155/–		≈3.3				156.4	124
Cu2(TPTC‐OnHex)	[Cu2(TPTC‐OnHex)]	H4tptc‐onhex	1083/1269							125
UPC‐21	[Cu2(pptc)]	H4pptc	1253.6/–						145	126, 127
BUT‐155	[Cu4(tdhb)]	H8tdhb	2070/–	0.82	9.5	16	470	0.28		128
Znpbdc‐8a	–	pbdc‐8a	856/–		9				112	129
FMOF‐1	{Ag2[Ag4(3,5‐tftz)6]}	3,5‐Htftz	810.5/–	0.324	12. × 8	6.6 × 4.9			158	80, 130, 131
FMOF‐2	[Ag(Ag3(3,5‐tftz)4)]	3,5‐Htftz			18	10				80
MAF‐4/ZIF‐8	[Zn(2‐mim)2]	2‐Hmim	–/1870	0.67	3.2	11.4	26	0.88		77
ZIF‐318	[Zn(2‐mim)(mim‐F3)]	2‐Hmim, 2‐Hmim‐F3	835/1007	0.37	9.3		23	0.58	68.4	132
ZIF‐68	[Zn(bim)(2‐nim)]	Hbim, 2‐Hnim			7.5	10.3	30 j)	0.52		133, 134
ZIF‐71	[Zn(4,5‐dcim)2]	4,5‐Hdcim	1183/1350	0.385	4.2	16.5	4.5	0.3		79, 133, 135, 136
ZIF‐90	[Zn(2‐cim)2]	2‐Hcim	1280/1466	0.485	3.5	11.2	331	0.35		79, 137
ZIF‐300	[Zn(2‐mim)0.86(5‐bbim)1.14]	5‐Hbbim, 2‐Hmim	420/490				6	0.58		138
ZIF‐301	[Zn(2‐mim)0.94(5‐cbim)1.06]	5‐Hcbim, 2‐Hmim	680/825				5.8	0.52		138
ZIF‐302	[Zn(2‐mim)0.67(5‐mbim)1.33]	5‐Hmbim, 2‐Hmim	240/270				4.5	0.53		138
MAF‐5	[Zn(2‐eim)2]	2‐Heim			2.2–4.9	7–10	≈0			139
MAF‐6	[Zn(2‐eim)2]	2‐Heim	1343/1695	0.61	7.6	18.4	16.2	≈0.5	143	78
[Ni8(L3)6]	[Ni8(OH)4(H2O)2(1,4‐bdp)6]	1,4‐H2bdp	1770/–				990	0.65		140
[Ni8(L4)6]	[Ni8(OH)4(H2O)2(bpdy)6]	H2bpdy	1920/–				936	0.5		140
[Ni8(L5)6]	[Ni8(OH)4(H2O)2(bpeb)6]	H2bpeb	2215/–		≈24		1129	0.7		140
[Ni8(L5‐CH3)6]	[Ni8(OH)4(H2O)2(bpdm)6]	H2bpdm	1985/–		≈24		720	0.7		140
[Ni8(L5‐CF3)6]	[Ni8(OH)4(H2O)2(bpdf)6]	H2bpdf	2195/–		≈24		862	0.83		140
Cu‐tebpz	[Cu2(tebpz)]	H2tebpz	576/–	0.37	4.6–13		6	0.5		141
Zn(NDI–SEt)	[Zn(ndi–SEt)]	H2ndi–SEt	888/–				237	0.4		142
MOFF‐3	[Cu(bptz‐F8)(H2O)]	H2bptz‐F8					37	0.3	135	112
MAF‐2	[Cu(3,5‐etz)]	3,5‐Hetz			1.5–4.2	9	7.4	0.5		143
MAF‐7	[Zn(3‐mtz)2]	3‐Hmtz	–/1870	0.67	3.4	11.2	443	0.33		77
MAF‐X5	[Zn(3,5‐dmtz)F]	3,5‐Hdmtz, F−	155/195		3.6					144
MAF‐52	[Cu7Cl(fmtz)6]	Hfmtz	1023/848	0.365	7.2 × 8.2, and 7.4 × 8.3	10.6	0.81		148	145
SCUTC‐18	[Zn2(1,4‐bdc)2(2,2′‐dmbpy)]	1,4‐H2bdc, 2,2′‐dmbpy	523/–		8.0					146
SCUTC‐19	[Zn2(1,4‐bdc)2(3,3′‐dm‐bpy)]	1,4‐H2bdc, 3,3′‐dm‐bpy	458/–		6.5					146
oCB‐MOF‐1,	[Zn4O2(1,4‐bdc)2(oCB‐L)2(DMF)2]	1,4‐H2bdc, oCB‐L	296/–		3.2 × 6.4	8.6	50	0.5	140	147
CID‐1	[Zn2(ip)2(4,4′‐bpy)2]	Hip, 4,4′‐bpy	300/–		5 × 6		64k)	0.61		148
[Cu(bpbtp)(L)(DMF)]	[Cu(bpbtp)(dbbpy‐F18)(DMF)]	H2bpbtp. dbbpy‐F18								149
[Cd(NO2‐bdc)(azbpy)]	[Cd(1,4‐NO2‐bdc)(azbpy)]	1,4‐H2bdc‐2‐NO2, 4,4′‐azbpy					149	0.32		150
SNU‐80	[Cu4(pa)8(teia)]	Hpa, teia	1035/1167	0.43			10	0.5		151
[Cu(bpy)2(otf)2]‐3D	[Cu(4,4′‐bpy)2(otf)2]	4,4′‐bpy, Hotf	740/–	0.27						152
DMOF‐TM2	[Zn2(1,4‐bdc‐(CH3)4)2(dabco)]	1,4‐H2bdc‐(CH3)4, dabco	1050	0.51	3.5		412	0.26		153
MOFF‐2	[Cu2(bpdc‐F8)2(dabco)]	H2bpdc‐F8, dabco	444/–				11	0.53	151	112
DUT‐30(Zn)	[Zn2(adb)2(dabco)]	H2adb, dabco	960/–	0.43			366	0.95		154
Zn‐dmpc	[Zn4O(dmpc)3]	H2dmpc	840/–	0.45	4 × 4	6	437	0.83		155
MAF‐X8	[Zn(mpba)]	H2mpba	1161/1306	0.47	6.7–8.8					156
MAF‐X10	[Zn4O(tmbpz)2(1,4‐bdc)]	1,4‐H2bdc, H2tmbpz	2032/–	0.80	6.6 × 5.8	9.4 × 9.9 × 13.2				157, 158
MAF‐X12	[Zn4O(tmbpz)2(1,4‐ndc)]	1,4‐H2ndc, H2tmbpz	1787/–	0.71	3.0 × 5.8	9.4 × 9.9 × 13.2				157
MAF‐X13	[Zn4O(tmbpz)2(bpdc)]	H2bpdc, H2tmbpz	2742/–	1.01	6.6 × 10.0	9.4 × 9.9 × 15.9				157
CALF‐25	–	optp	385/–		4.6 × 3.9		76.9	0.73		85
CALF‐30	[Cu3(btp‐iPr)2]	H3btp‐iPr	244/300		3.57					159
CALF‐33‐Et3	[Cu3(L1‐Et3)2]	H3L1‐Et3	842/1030		7.2 × 16.1					160

^a)1,4‐H₂bdc‐2‐NO₂, 2‐nitro terephthalic acid; 1,4‐H₂bdc‐(C₂H₅)₂, 2,5‐diethylterephthalic acid; 1,4‐H₂bdc‐C₂F₅, 2‐pentafluoroethylterephthalic acid; H₂ma, propanedioic acid; 1,4‐H₂bdc‐(CF₃)₂, 2,5‐bis(trifluoromethyl)terephthalic acid; 1,4‐H₂bdc‐CH₃, 2‐methyl‐terephthalic acid; 1,4‐H₂bdc‐(CH₃)₂, 1,4‐H₂bdc‐(CH₃)₄, 2,3,5,6‐tetramethylterephthalic acid; 2,5‐dimethyl‐terephthalic acid; 1,4‐H₂bdc‐CF₃, 2‐trifluoromethyl‐terephthalic acid; 1,4‐H₂bdc‐F₄, 2,3,5,6‐tetrafluoroterephthalic acid; 2,6‐H₂ndc, 2,6‐naphthalenedicarboxylic acid; H₂bn, 1,1′‐binaphthyl‐4,4′‐dicarboxylic acid; 3‐Hmtz, 3‐methyl‐1,2,4‐triazole; 2‐Hmim, 2‐methylimidazole; 2‐Hmim‐F₃, 2‐trifluoromethylimidazole; 2‐Hvim, 2‐vinyl‐imidazole; 2‐Hmimc, 4‐methyl‐5‐imidazolecarboxaldehyde; H₂hfipbb, 4,4′‐(hexafluoroisopropylidene)bis(benzoic acid); 1,4‐H₂bdp, 1,4‐bis(4‐pyrazolyl)benzene; H₂bpdy, 4,4′‐buta‐1,3‐diyne‐1,4‐diylbis(1H‐pyrazole); H₂bpeb, 1,4‐bis((1H‐pyrazol‐4‐yl)ethynyl)benzene; H₂bpdm, 4,4′‐(2,5‐dimethyl‐1,4‐phenylene)bis(ethyne‐2,1‐diyl)bis(1H‐pyrazole); H₂bpdf, 4,4′‐(2,5‐bis(trifluoromethyl)‐1,4‐phenylene)bis(ethyne‐2,1‐diyl)bis(1H‐pyrazole); H₃btmb, 1,3,5‐tris(3‐carboxyphenyl)benzene; pbdc, polymeric bdc‐acid; oCB‐L, 1,2‐bis{(pyridin‐3‐yl)methanol}‐1,2‐dicarba‐closo‐dodecarborane, Hip, isophthalic acid; 4,4′‐bpy, 4,4′‐bipyridine; 2,2′‐dm‐bpy, 2,2′‐dimethyl‐4,4′‐bipyridine; 3,3′‐dm‐bpy, 3,3′‐dimethyl‐4,4′‐bipyridine; H₂bpdc‐F₈, 2,2′,3,3′,5,5′,6,6′‐octafluorobiphenyl‐4,4′‐dicarboxylic acid; H₂bptz‐F₈, 5,5′‐(perfluorobiphenyl‐4,4′‐diyl)bis(1H‐tetrazole); dabco, 1,4‐diazabicyclo[2.2.2]octane; H₂bpbtp, 2,5‐bis(perfluorobutyl)terephthalic acid, dbbpy‐F₁₈, 2,5‐bis(perfluorobutyl)‐1,4‐bis(4‐pyridyl)benzene; 4,4′‐azbpy, 4,4′‐azobipyridine; H₃btc, 1,3,5‐benzenetricarboxylic acid; H₃mbtc, methyl‐1,3,5‐benzenetricarboxylic acid; H₃ebtc, ethyl‐1,3,5‐benzenetricarboxylic acid; H₃NH₂btc, 2‐aminobenzene‐1,3,5‐tricarboxylic acid; H₄tptc‐oⁿhex, 2′,5′‐di‐n‐hexyloxy‐[1,1′:4′,1′‐terphenyl]‐3,3″,5,5″‐tetracarboxylic acid; teia, 1,3,5,7‐tetrakis(4‐(2‐ethyl‐1H‐imidazol‐1‐yl)phenyl)‐adamantane; Hpa, pivalic acid; H₂tpda, 4,4′‐(3,5‐bis(trifluoromethyl)phenylazanediyl)dibenzoic acid; H₂ope‐C₁₈, 4,4′‐(2,5‐bis(octadecyloxy)‐1,4‐phenylene)bis(ethyne‐2,1‐diyl)dibenzoic acid; H₂mpba, 4‐(3,5‐dimethylpyrazol‐4‐yl)benzoic acid; H₂glu, glutaric acid; H₂abdc‐(CF₃)₂, 2,2′‐bistrifluoromethyl‐4,4′‐azobenzenedicarboxylic acid; H₂tmbpz, 3,3′,5,5′‐tetramethyl‐4,4′‐bipyrazole; H₂bpdc, biphenyl‐4,4′‐dicarboxylic acid; 3,5‐Hdmtz, 3,5‐dimethyl‐1,2,4‐triazole; Hfmtz, 3‐methyl‐5‐trifluoromethyl‐1,2,4‐triazole; H₂adb, 4,4′‐(anthracene‐9,10‐diyl)dibenzoic acid; H₃btp‐ⁱPr, isopropyl benzene‐1,3,5‐triyltris(hydrogen phosphonate); optp, octaethyl pyrene‐1,3,6,8‐tetraphosphonate; H₂tmbpd, 3,3′,5,5′‐tetrakis(methylthio)biphenyl‐4,4′‐dicarboxylic acid; H₂CH₃PhTDC, 3‐methyl‐4‐phenylthieno[2,3‐b]thiophene‐2,5‐dicarboxylic acid; H₂tbip, 5‐tert‐butyl isophthalic acid; 3,5‐Hetz, 3,5‐diethyl‐1,2,4‐triazole; H₂bbpdc, 4′‐tert‐butyl‐biphenyl‐3,5‐dicarboxylic acid; Hotf, trifluoromethanesulfonic acid; H₂dmpc, 3,5‐dimethyl‐1H‐pyrazole‐4‐carboxylic acid; H₄pptc, pentiptycene‐based tetracarboxylic acid; 2‐Hnim, 2‐nitroimidazole; Hbim, benzimidazole; 2‐Heim, 2‐ethylimidazole; H₂tebpz, 3,3′,5,5′‐tetraethyl‐4,4′‐bipyrazole; 3,5‐Htftz, 3,5‐bis(trifluoromethyl)‐1,2,4‐triazole; 4,5‐Hdcim, 4,5‐dichloroimidazole; 1,3‐H₂bdb, 1,3‐di(4‐carboxyphenyl)benzene; 2,7‐H₂ndb, 2,7‐di(4‐carboxyphenyl)naphthalene; H₃ctta, 5′‐(4‐carboxyphenyl)‐2′,4′,6′‐trimethyl‐[1,1′:3′,1″‐terphenyl]‐4,4″‐dicarboxylic acid; H₃ttna, 6,6′,6″‐(2,4,6‐trimethylbenzene‐1,3,5‐triyl)tris(2‐naphthoic acid); H₈tdhb, 3,3′,5,5′‐tetrakis(3,5‐dicarboxyphenyl)‐2,2′,4,4′,6,6′‐hexamethylbiphenyl; 2‐Hcim, imidazole‐2‐carboxaldehyde; 5‐Hbbim, 5‐bromobenzimidazol; 5‐Hcbim, 5‐chlorobenzimidazole; 5‐Hmbim, 5‐methylbenzimidazole; Hbtz, 1H‐benzotriazole; RR‐H₂cam, (1R,3R)‐1,2,2‐trimethyl‐1,3‐cyclopentanedicarboxylic acid; H₂bim, 1,2‐bis((5H‐imidazol‐4‐yl)methylene)hydrazine; 2‐H₂bmim, 1,2‐bis((2‐methyl‐1H‐imidazol‐4‐yl)methylene)hydrazine; DIFP, diisopropylfluorophosphate; DES, diethylsulfide; H₄tcpp, tetrakis(4‐carboxyphenyl)porphyrin

^b) S _BET and S _L stand for the BET and Langmuir surface areas, respectively

^c) V _p stands for the pore volume

^d) d _a stands for the size of the aperture or channel

^e) d _p stands for the size of the cavity

^f) $C_{{\text{H}}_2\text{O}}$ stands for the water adsorption capacity near saturation pressure and room temperature unless otherwise specified

^g)α stands for the relative pressure at which half of the water adsorption capacity at saturation pressure is reached; $C_{{\text{H}}_2\text{O}}$ and α are obtained by reference values or by scanning the reported adsorption isotherm with the software ScanIt

^h)CA stands for the water contact angle

ⁱ⁾Qualitative data were not provided

^j) $C_{{\text{H}}_2\text{O}}$ at 0.7 P/P ₀

^k) $C_{{\text{H}}_2\text{O}}$ at 0.63 P/P ₀.