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. Author manuscript; available in PMC: 2020 Nov 20.
Published in final edited form as: J Am Chem Soc. 2019 Nov 6;141(46):18551–18559. doi: 10.1021/jacs.9b09385

Figure 4.

Figure 4.

A) Retrosynthetic analysis of azaphilone natural product lunatoic acid A (25). B) Total synthesis of lunatoic acid A (25). C) Calculated and measured CD data for lunatoic acid A methyl ester* (28). *NADPH recycling system: G6P (2 equiv), NADP(+) (0.4 equiv), G6PDH (1 U/mL)