Table 3.
Description and terpenoid quantitation (expressed in µg/L) in white wine1 using the online HS–SPME sample preparation method and offline SPE sample preparation method, respectively.
Online HS–SPME | ||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
FLY16S | ARV16S | ANI16/17S | JCB16CH | FRN17SB | FLK17AL | KZC18CB | KLA16S | ORB17AL | LNC17SB | ARV16S/B | GWZ19C | GWC19E | MRF17SB | |
Limonene | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | 0.27 | <LOQ | <LOQ | <LOQ | <LOQ | 24.39 | 0.13 | 0.01 | <LOQ |
6-Methyl-5-hepten-2-one | <LOQ | <LOQ | 0.06 | <LOQ | <LOQ | 0.8 | 0.46 | <LOQ | <LOQ | <LOQ | 0.31 | 0.87 | 1.06 | <LOQ |
Fenchone | <LOQ | <LOD | <LOD | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
cis-Linalool oxide | 20.79 | 8.1 | 18.93 | 6.58 | 4.84 | 20.56 | <LOD | 19.08 | 2.84 | 10.33 | 14.01 | 5.53 | 2.34 | 3.69 |
trans-Linalool oxide | 6.14 | 3.07 | 5.96 | 2.84 | 1.77 | 21.38 | 0.78 | 5.38 | 4.71 | 3.86 | 4.81 | 3.24 | 2.22 | 1.7 |
Linalool | 0.29 | 0.82 | 1.31 | 1.93 | 2.06 | 37.9 | 2.44 | 2.13 | 15.22 | 3.49 | 0.1 | 22.04 | 14.6 | 3.96 |
Linalyl acetate | <LOQ | <LOQ | <LOQ | <LOD | <LOD | <LOD | <LOD | <LOQ | <LOD | <LOQ | <LOQ | <LOQ | <LOQ | <LOD |
α-Terpineol | 2.92 | 4.03 | 4.11 | 4.97 | 3.18 | 56.23 | 0.91 | 4.73 | 11.79 | 12.68 | 5.21 | 10.76 | 6.3 | 3.46 |
β-Citronellol | 1.35 | 0.76 | 1.73 | 1.81 | 1.75 | 5.27 | 2.13 | 1.61 | 3.13 | 2.24 | 0.52 | 34 | 75.43 | 3.69 |
Nerol | 0.76 | 2.08 | <LOD | 5.05 | 5.55 | 7.82 | 0.76 | 3.46 | 2.92 | 7.19 | 2.1 | 13.78 | 21.04 | <LOD |
β-Damascone | 0.01 | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
β-Damascenone | 0.64 | 0.75 | 0.66 | 0.74 | 0.27 | 1.31 | 0.35 | 1.69 | 1.68 | <LOQ | 2.45 | 3.24 | 1.75 | 1.45 |
Geraniol | 3.27 | 64.39 | 9.45 | 5.41 | 6.49 | 20.21 | 3.48 | 3.56 | 8.67 | 7.77 | 78.95 | 60.22 | 63.37 | 13.14 |
α-Ionone | 0.04 | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
β-Ionone | 0.26 | 0.06 | 0.04 | 0.13 | 0.03 | 0.03 | 0.03 | 0.04 | 0.03 | 0.01 | 0.32 | 0.02 | 0.02 | 0.03 |
cis-Pseudoionone | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 0.36 | <LOD | <LOD | <LOD |
trans-Pseudoionone | 0.27 | 0.34 | 1.02 | 0.35 | 0.23 | 0.18 | 0.32 | 0.2 | 0.16 | 0.19 | 1.11 | 0.29 | 0.29 | 0.28 |
Farnesol (Z,E) | 0.11 | <LOD | 0.05 | 0.63 | 0.1 | 0.29 | 0.21 | 0.06 | 0.42 | 0.03 | 0.03 | 0.01 | 0.01 | 0.62 |
Farnesol (E,Z) | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 0.32 | <LOD | <LOD | <LOD |
Farnesol (E,E) | 0.15 | 0.11 | 0.4 | 1.77 | 0.53 | 0.69 | 3.66 | 0.09 | 1.87 | 0.06 | 0.91 | 3.12 | 3.24 | 1.87 |
Offline SPE | ||||||||||||||
FLY16S | ARV16S | ANI16/17S | JCB16CH | FRN17SB | FLK17AL | KZC18CB | KLA16S | ORB17AL | LNC17SB | ARV16S/B | GWZ19C | GWC19E | MRF17SB | |
Limonene | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
6-Methyl-5-hepten-2-one | <LOD | <LOD | <LOQ | 0.02 | <LOD | 0.91 | 0.53 | <LOD | <LOD | <LOD | 0.07 | 1.68 | 1.63 | <LOD |
Fenchone | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD |
cis-Linalool oxide | 24.5 | 11.01 | 19.81 | 11.12 | 8.11 | 30.41 | 0.07 | 16.48 | 4.24 | 18.26 | 12.89 | 1.39 | 0.87 | 5.17 |
trans-Linalool oxide | 8.23 | 3.48 | 5.84 | 4.1 | 2.7 | 21.62 | 0.19 | 5.15 | 1.32 | 4.65 | 4.33 | 1.45 | 1.18 | 1.19 |
Linalool | 1.45 | 1.66 | 2.37 | 4.22 | 3.41 | 63.16 | 4.04 | 8.02 | 21.51 | 5.33 | 0.62 | 19.09 | 12.43 | 6.01 |
Linalyl acetate | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD |
α-Terpineol | 3.46 | 4.7 | 4.87 | 5.97 | 2.99 | 85.92 | <LOQ | 7.01 | 14.83 | 18.97 | 6.02 | 3.81 | 1.72 | 3.4 |
β-Citronellol | 2.12 | 1.47 | 2.36 | 2.35 | 2.32 | 5.98 | 2.64 | 2.81 | 3.29 | 2.68 | 1.23 | 48.86 | 92.34 | 3.7 |
Nerol | <LOD | <LOD | <LOD | <LOD | <LOD | 5.92 | <LOD | <LOD | 2.88 | <LOD | <LOD | 18 | 24.25 | <LOD |
β-Damascone | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ | <LOQ |
β-Damascenone | 0.98 | 1.19 | 1.19 | 1.07 | 0.71 | 1.61 | 0.86 | 2.42 | 1.68 | 0.36 | 2.97 | 3.79 | 2.01 | 1.47 |
Geraniol | <LOD | 9.63 | 0.42 | 1.56 | 1.71 | 14.72 | 2.83 | <LOD | 6.01 | 3.5 | 13.68 | 66.92 | 60.07 | 4.78 |
α-Ionone | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 0.79 | 0.75 | <LOD |
β-Ionone | <LOD | <LOD | <LOD | <LOD | <LOD | 0.42 | <LOD | 0.47 | <LOD | <LOD | 0.51 | <LOD | <LOD | <LOD |
cis-Pseudoionone | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 1.48 | 1.41 | <LOD |
trans-Pseudoionone | 0.72 | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 0.74 | <LOD | <LOD |
Farnesol (Z,E) | 0.59 | <LOD | <LOD | 0.62 | <LOD | 0.58 | <LOD | <LOD | 0.73 | 0.7 | <LOD | 0.68 | 0.71 | 0.85 |
Farnesol (E,Z) | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | <LOD | 0.77 | <LOD | <LOD |
Farnesol (E,E) | 0.13 | 0.23 | 0.24 | 0.91 | 0.51 | 0.59 | 2.44 | 0.42 | 1.36 | 0.19 | 0.16 | 12.06 | 12.07 | 1.84 |
1 See Table S2 in Supplementary Materials section for the wine description.