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. 2020 Jan 24;25(3):511. doi: 10.3390/molecules25030511

Table 4.

ΔH, ΔG, and TΔS values for Eph protonation and its complexes with UO22+ in NaClaq at I = 0.5 mol dm−3 and T = 298.15 K.

Species 1 ΔH 2 ΔG 2 TΔS2
LH −39 ± 1 −57.69 ± 0.05 19 ± 3
LH2 −67 ± 1 −107.39 ± 0.05 40 ± 3
ML −26 ± 4 −69.16 ± 0.02 43 ± 10
M2L2(OH)2 39 ± 2 −92.21 ± 0.02 131 ± 6

1 log βpqr refers to equilibrium: p Mm+ + q Lz− + r H+ = MpLqHr(mp-zq+r); 2 in kJ mol−1; ±95% confidence interval.