Table 4.
Species 1 | ΔH 2 | ΔG 2 | TΔS2 |
---|---|---|---|
LH | −39 ± 1 | −57.69 ± 0.05 | 19 ± 3 |
LH2 | −67 ± 1 | −107.39 ± 0.05 | 40 ± 3 |
ML | −26 ± 4 | −69.16 ± 0.02 | 43 ± 10 |
M2L2(OH)2 | 39 ± 2 | −92.21 ± 0.02 | 131 ± 6 |
1 log βpqr refers to equilibrium: p Mm+ + q Lz− + r H+ = MpLqHr(mp-zq+r); 2 in kJ mol−1; ±95% confidence interval.