Table 3.
Isotherm | Parameters | 293 (K) | 313 (K) | 333 (K) |
---|---|---|---|---|
NaP1 | ||||
Langmuir | KL (L/mg) | 0.456 | 0.283 | 0.145 |
RL | 0.263 | 0.365 | 0.528 | |
qe (mg/g) | 62.45 | 62.17 | 64.19 | |
R2 | 0.984 | 0.973 | 0.886 | |
Freundlich | n | 2.027 | 1.652 | 1.153 |
KF (mg/g(L/mg)1/n) | 15.04 | 12.48 | 9.79 | |
R2 | 0.808 | 0.796 | 0.881 | |
Temkin | A (L/g) | 20.89 | 0.47 | 4.49 |
B (J/mol) | 8.53 | 8.58 | 11.66 | |
R2 | 0.931 | 0.937 | 0.945 | |
Dubinin-Radushkievich | Xm (mg/g) | 239.1 | 131.2 | 43.2 |
E (kJ/mol) | 11.7 | 10.3 | 8.7 | |
R2 | 0.828 | 0.830 | 0.900 | |
NaP1CS | ||||
Langmuir | KL (L/mg) | 0.160 | 0.152 | 0.166 |
RL | 0.504 | 0.516 | 0.495 | |
qe (mg/g) | 35.35 | 37.76 | 37.60 | |
R2 | 0.976 | 0.974 | 0.988 | |
Freundlich | n | 3.103 | 2.703 | 2.293 |
KF (mg/g(L/mg)1/n) | 7.59 | 7.01 | 6.56 | |
R2 | 0.871 | 0.793 | 0.734 | |
Temkin | kT (L/g) | 38.42 | 15.03 | 9.92 |
B (J/mol) | 3.52 | 4.44 | 4.84 | |
R2 | 0.949 | 0.929 | 0.919 | |
Dubinin-Radushkievich | Xm (mg/g) | 1043.3 | 766.5 | 540.2 |
E (kJ/mol) | 13.9 | 12.6 | 11.5 | |
R2 | 0.893 | 0.827 | 0.779 |