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. 2020 Feb 1;13(3):643. doi: 10.3390/ma13030643

Table 3.

Comparison of estimated parameters obtained from the Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherms for Cu(II) on NaP1 and NaP1CS.

Isotherm Parameters 293 (K) 313 (K) 333 (K)
NaP1
Langmuir KL (L/mg) 0.456 0.283 0.145
RL 0.263 0.365 0.528
qe (mg/g) 62.45 62.17 64.19
R2 0.984 0.973 0.886
Freundlich n 2.027 1.652 1.153
KF (mg/g(L/mg)1/n) 15.04 12.48 9.79
R2 0.808 0.796 0.881
Temkin A (L/g) 20.89 0.47 4.49
B (J/mol) 8.53 8.58 11.66
R2 0.931 0.937 0.945
Dubinin-Radushkievich Xm (mg/g) 239.1 131.2 43.2
E (kJ/mol) 11.7 10.3 8.7
R2 0.828 0.830 0.900
NaP1CS
Langmuir KL (L/mg) 0.160 0.152 0.166
RL 0.504 0.516 0.495
qe (mg/g) 35.35 37.76 37.60
R2 0.976 0.974 0.988
Freundlich n 3.103 2.703 2.293
KF (mg/g(L/mg)1/n) 7.59 7.01 6.56
R2 0.871 0.793 0.734
Temkin kT (L/g) 38.42 15.03 9.92
B (J/mol) 3.52 4.44 4.84
R2 0.949 0.929 0.919
Dubinin-Radushkievich Xm (mg/g) 1043.3 766.5 540.2
E (kJ/mol) 13.9 12.6 11.5
R2 0.893 0.827 0.779