Table 4.
Isotherm | Parameters | 293 (K) | 313 (K) | 333 (K) |
---|---|---|---|---|
NaP1 | ||||
Langmuir | KL (L/mg) | 0.002 | 0.001 | 1.510 |
RL | 0.980 | 0.983 | 0.051 | |
qe (mg/g) | 8.40 | 6.60 | 4.60 | |
R2 | 0.629 | 0.626 | 0.999 | |
Freundlich | n | 0.780 | 0.844 | 7.169 |
KF (mg/g(L/mg)1/n) | 228.81 | 145.46 | 2.22 | |
R2 | 0.966 | 0.903 | 0.927 | |
Temkin | A (L/g) | 22.832 | 20.535 | 93.076 |
B (J/mol) | 2.17 | 1.87 | 0.47 | |
R2 | 0.683 | 0.805 | 0.951 | |
Dubinin-Radushkievich | Xm (mg/g) | 806.5 | 1119.1 | 1014.5 |
E (kJ/mol) | 5.8 | 6.1 | 18.6 | |
R2 | 0.945 | 0.872 | 0.952 | |
NaP1CS | ||||
Langmuir | KL (L/mg) | 0.012 | 0.020 | 0.004 |
RL | 0.868 | 0.804 | 0.953 | |
qe (mg/g) | 14.00 | 26.00 | 4.20 | |
R2 | 0.700 | 0.848 | 0.505 | |
Freundlich | n | 0.560 | 2.983 | 0.821 |
KF (mg/g(L/mg)1/n) | 1204.32 | 2.67 | 252.05 | |
R2 | 0.889 | 0.939 | 0.951 | |
Temkin | kT (L/g) | 19.574 | 1.720 | 20.485 |
B (J/mol) | 4.02 | 2.54 | 1.36 | |
R2 | 0.900 | 0.937 | 0.855 | |
Dubinin-Radushkievich | Xm (mg/g) | 85.2 | 2146.7 | 1194.1 |
E (kJ/mol) | 4.9 | 7.9 | 5.8 | |
R2 | 0.900 | 0.938 | 0.962 |