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. 2020 Feb 1;13(3):643. doi: 10.3390/ma13030643

Table 4.

Comparison of estimated parameters obtained from the Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherms for phenol on NaP1 and NaP1CS.

Isotherm Parameters 293 (K) 313 (K) 333 (K)
NaP1
Langmuir KL (L/mg) 0.002 0.001 1.510
RL 0.980 0.983 0.051
qe (mg/g) 8.40 6.60 4.60
R2 0.629 0.626 0.999
Freundlich n 0.780 0.844 7.169
KF (mg/g(L/mg)1/n) 228.81 145.46 2.22
R2 0.966 0.903 0.927
Temkin A (L/g) 22.832 20.535 93.076
B (J/mol) 2.17 1.87 0.47
R2 0.683 0.805 0.951
Dubinin-Radushkievich Xm (mg/g) 806.5 1119.1 1014.5
E (kJ/mol) 5.8 6.1 18.6
R2 0.945 0.872 0.952
NaP1CS
Langmuir KL (L/mg) 0.012 0.020 0.004
RL 0.868 0.804 0.953
qe (mg/g) 14.00 26.00 4.20
R2 0.700 0.848 0.505
Freundlich n 0.560 2.983 0.821
KF (mg/g(L/mg)1/n) 1204.32 2.67 252.05
R2 0.889 0.939 0.951
Temkin kT (L/g) 19.574 1.720 20.485
B (J/mol) 4.02 2.54 1.36
R2 0.900 0.937 0.855
Dubinin-Radushkievich Xm (mg/g) 85.2 2146.7 1194.1
E (kJ/mol) 4.9 7.9 5.8
R2 0.900 0.938 0.962