Table 1.
Compound | UV/vis spectra in toluene | fluorescence spectra in toluene | |||
---|---|---|---|---|---|
λmax (nm) | λex (nm) | λem (nm) | τ (ns) | φ (%) | |
PTC-1(2H) | 397, 506, 542, 580, 635 | 405 | 638, 702 | 9.80 | 1.82 |
H2CBPP | 412, 504, 540, 579, 635 | 405 | 638, 700 | 9.87 | 1.86 |
Compound | CV spectraa (vs. SCE) | TA spectra in toluene | |||
---|---|---|---|---|---|
Red1 (V) | Oxd1 (V) | TA band (nm) in N2 | τ (μs)b | τ (μs)c | |
PTC-1(2H) | −0.97 | 0.98 | 430–500 | 102.20 | 0.33 |
H2CBPP | −0.98 | 1.10 | 425–500 | 53.98 | 0.25 |
aIn CH2Cl2.
bIn N2.
cIn air.