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. 2020 Feb 18;2020:8321732. doi: 10.1155/2020/8321732

Table 5.

Identification of chemical compositions of fractions from celery seeds.

No. RTa (min) Compound Peak Areab (%)
PW PB PE PP
1 0.69 6-Hydroxyangelicin 0.40
2 0.89 Mannitol 0.43
3 0.91 3-Buten-2-one 1-(2,3,6-trimethyl phenyl) 1.37 0.23
4 0.96 Lactulose 0.28
5 0.97 Ectoine 1.81
6 0.98 Heptyl formate 0.45 0.38
7 0.99 Genipic acid 0.45
8 1.00 2,4-Diethylthiazole 1.56
9 1.05 2,5-Dioxopentanoate 2.18
10 1.24 2-Hydroxyethanesulfonate 0.40 0.39
11 1.27 2,6-Piperidinedicarboxylic acid 1.09
12 1.37 Pregabalin 1.99
13 1.38 N-acetylhistamine 1.46
14 1.38 Nipecotic acid 11.99 1.51
15 1.39 4-Guanidinobutanoic acid 0.25
16 1.44 Gln gly 1.87
17 1.52 Cytarabine 0.74
18 1.62 Ser val gly 2.46
19 1.74 Ormetoprim 0.29
20 2.02 6-Hydroxynicotinic acid 0.33
21 2.54 3,3,5-Triiodo-L-thyronine-beta-D-glucuronoside 0.35
22 3.13 2-Phenylacetamide 0.63 0.52 3.86 0.10
23 4.1 (S)-5′-deoxy-5'-(methylsulfinyl)adenosine 0.54
24 4.12 Adenine 1.88
25 4.12 Adenosine 0.39 14.99 0.47
26 4.19 Cordycepin 0.32
27 4.31 Patulin 0.42
28 4.34 4-Pyridoxic acid 0.27 0.36
29 4.35 Inosine 0.94
30 4.36 3′-Deoxyadenosine 0.41
31 4.39 α-[1-(ethylamino)ethyl]-p-hydroxy- benzyl alcohol 0.56
32 4.93 Selfotel 1.51
33 4.98 2-Acetyl-1-ethylpyrrole 3.72 0.30 5.22 0.08
34 4.99 3-Aminobenzamide 0.87 0.93
35 5.01 4-Hydroxydihydrocinnamaldehyde 0.36
36 5.11 Imidazoleacetic acid 0.79
37 5.16 Mequinol 0.34 2.55
38 5.36 2-Pyrocatechuic acid 0.62 0.85
39 5.36 L-tryptophan 1.52 0.44
40 5.39 Imidacloprid-guanidine 0.39 0.27 1.07
41 5.50 Dopamine 0.50
42 5.76 Methiocarb-sulfoxide 0.45
43 5.81 3-(4-methoxy-6-oxopyran-2-yl)butanoic acid 0.51
44 6.24 1-naphthylmethanol 0.89
45 6.41 1H-indole-3-carboxaldehyde 2.65 0.32 1.86 0.38
46 6.73 n-Acetylhomoproline 0.23
47 6.77 Methyl 3-methyl-1-butenyl disulfide 0.75 0.28
48 6.82 Aesculin 0.66
49 6.87 Oleic acid 0.47
50 6.89 Beta-carboline 0.86
51 6.98 3-Carboxypropyl trimethylammonium 0.43 0.39
52 6.99 Apigenin 8.48 11.28
53 7.28 trans-O-hydroxybenzylidenepyruvate 0.35
54 7.31 Eugenitol 0.85 0.22 0.84
55 7.54 Glycolic acid 0.18
56 7.59 2-Ketobutyric acid 0.12
57 7.61 Indoleacetic acid 0.44 0.43
58 7.62 4-Methyl-1-phenyl-2-pentanone 1.35
59 7.66 3-Methyl-1-phenyl-3-pentanol 8.05 0.72
60 7.69 3′-Methoxy-E,E-dienoestrol 0.36 0.70
61 7.79 2-Butyl-1-octanol 0.38 0.52
62 7.80 2-Hydroxy-8-methylchromene-2-carboxylate 0.43 1.91
63 7.84 Diflufenican 1.78 0.82
64 7.89 3-Methylbenzaldehyde 0.40 0.42
65 7.98 Luteolin 7-galactoside 6.59 2.42 0.76
66 7.99 2-Naphthol 2.30 0.24 0.94
67 8.16 Apiin 2.34 3.64 0.78
68 8.17 Ambolin 6.72 1.49
69 8.19 2-Hydroxymuconate semialdehyde 1.29 5.21 1.53
70 8.20 Decanoic acid, 3-amino-, (S)- 0.66 2.77
71 8.21 Indoleacrylic acid 0.54 1.82
72 8.22 Glycine 0.11
73 8.27 Aesculetin 0.11 0.56 4.32 13.28
74 8.27 Pelargonidin 3-O-glucoside 2.08 2.61
75 8.32 Peonidin-3-O-beta-galactopyranoside 0.18 1.95 2.97
76 8.46 2-Butyl-3-phenyl-2-propen-1-al 0.79 0.35 0.95
77 8.61 1,6-Dimethoxypyrene 0.30 2.08
78 8.65 Foliosidine 0.51 1.76
79 8.72 Ensulizole 2.23 1.53
80 8.73 3-Hydroxypropionic acid 2.61
81 8.84 Flavan skeleton 0.40 1.82
82 8.92 Chalconaringenin 4.87
83 9.01 Peonidin 3-(6″-acetylglucoside) 1.82
84 9.27 Mesylate 7.13 3.03 0.59
85 9.33 15-Methylpalmitate (2R,3R)-2-(3,4-dihydroxyphenyl)-3,5- 0.12 7.18 2.26
86 9.40 Dihydroxy-7-methoxy-2,3-dihydrochromen-4-one 1.86 1.17
87 9.70 α-Terpinene 0.45 0.51 0.37 0.47
88 9.80 4-Methyl-N-ethylcathinone 0.54 1.43 0.86
89 9.93 Perillyl acetate 0.65 0.26 1.39
90 10.27 5,6,7,8-Tetrahydro-2-naphthol 1.12 2.36 1.49
91 10.52 Cicaprost 0.25 2.47
92 13.72 Erucamide 2.27 0.75 0.80 0.09
93 13.91 Oxoproline 0.16
94 14.52 (2R,3S)-2-Hydroxy-3-isopropylbutanedioic acid 0.16
95 15.44 Vanillin 0.39
96 15.51 Lauric acid 0.17
97 15.80 DL-anabasine 1.79
98 15.93 Phthalic acid 0.35
99 16.01 Methyl jasmonate 1.44
100 16.23 D-arabitol 0.58
101 16.24 Ribitol 0.42
102 16.59 N-(2-hydroxyethyl)-iminodiacetic acid 0.10
103 16.68 Farnesal 19.37
104 16.72 S-carboxymethylcysteine 0.17
105 16.87 Gentisic acid 1.81
106 16.97 terephthalic acid 1.10
107 17.07 Farnesol 0.40
108 17.13 N-acetylisatin 0.16
109 17.64 Myristic acid 0.47
110 17.76 Fructose 0.78
111 18.08 Butylphthalide 18.42
112 18.09 Galactose 0.10
113 18.59 Coniferyl alcohol 0.82
114 18.70 1-Hexadecanol 0.12
115 19.45 4-Hydroxymethyl-3-methoxyphenoxyacetic acid 13.54
116 19.62 Palmitic acid 0.64
117 19.94 Myo-inositol 0.08
118 20.61 6-Hydroxy caproic acid dimer 0.35
119 21.17 Linoleic acid 0.78
120 21.40 Stearic acid 0.76
121 28.89 Cholestan-3beta-ol 0.25
122 30.62 Cholestane-3,5,6-triol, (3beta, 5alpha,6beta)- 0.82
Total 84.35 81.88 75.86 94.32

RTa: retention time (min); Peak Areab: the average of the percentage of peak area relative to the total peak area (n = 3); “—“: not detected.