. Author manuscript; available in PMC: 2021 Jan 27.

Published in final edited form as: Angew Chem Int Ed Engl. 2019 Dec 16;59(5):2033–2038. doi: 10.1002/anie.201912618

Table 2.

Scope of the Allylic Chloride^a

^(a)

Isolated yields on 0.2 mmol scale. SFC analysis was used to determine ee.

^(b)

Absolute stereochemistry was determined by X-ray diffraction.

^(c)

With 10 mol % CuCl₂, 12 mol % L8, and 26 mol % LiHMDS.

^(d)

synthesized from a mixture of linear and branched allylic chlorides (see the SI for more details).