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. 2020 Feb 3;11(8):2028–2044. doi: 10.1039/d0sc00022a

Table 1. Energy density calculations for recently reported AZIB cathodes for various amounts of Zn in the anode.

Cathode Avg. V (V vs. Zn/Zn2+) Avg. Q (mA h g–1) Current density (A g–1) Mass loading (mg cm–2) Theoretical Zn (mg) EDtheoretical (W h kg–1) ED50μm-Zn (W h kg–1) ED250μm-Zn (W h kg–1) Ref.
Zn0.25V2O5·nH2O 0.81 282 0.3 6.0 2.334 170 33.1 7.31 13
ZnMn2O4 1.35 150 0.05 1.08 0.4794 167 10.8 2.21 31
α-MnO2 1.44 260 0.308 3.0 1.076 284 29.2 6.09 16
Na2V6O16·3H2O 0.80 341 0.5 2.653 1.248 193 19.01 3.929 59
Mn-VOx 0.75 371 0.5 3.5 1.792 192 25.03 5.26 60
δ-MnO2 (birnessite) 1.5 350 0.1 2.0 0.9675 368 28.07 5.72 17
Zn0.3V2O5·nH2O 0.80 426 0.2 2.0 1.176 224 18.22 3.714 61
ZnHCF 1.7 65 0.06 8.0 anode: 0.7 a 102 (actual) 62
Na0.33V2O5 0.7 276 0.2 1.5 0.5712 144 7.85 1.584 63
CoFe(CN)6 1.75 173 0.3 n/a, assume 2.0 0.4774 250 16.19 3.30 64
VO2 (B) 0.75 357 0.1 n/a, assume 2.0 0.9851 187 14.31 2.918 14
LiV2(PO4)3/C 1.3 42-Stack pouch cell 156 (actual) 65
β-MnO2 1.35 258 0.2 2.0 0.7119 265 18.6 3.8 18
δ-MnO2–x 1.5 345 0.2 1.0 0.421 364 12.6 2.51 66
NaCa0.6V6O16·nH2O 0.75 347 0.1 1.1 0.5266 183 7.84 1.57 67
Cu3(HHTP)2 0.80 191 0.1 2.0 0.528 124 8.17 1.665 68
MnO2H0.16-(H2O)0.27 1.35 236 0.1 2.5 0.814 247 21.01 4.329 69
p-Chloranil 1.1 170 0.0434 2.4 0.563 155 11.87 2.44 70
Li–V2O5·nH2O 0.7 470 0.5 0.735 0.477 209 6.69 1.327 71
PANI–MnO2 1.5 280 0.2 2.0 0.7726 313 22.5 4.58 72
Calix[4]Quinone 1.0 335 0.02 2.5 1.156 238 22.1 4.55 73
H2V3O8 0.7 400 0.1 1.2 0.6623 188 9.18 1.84 21
V6O13 0.7 360 0.2 1.25 0.6209 175 8.59 1.72 15
MgxV2O5·nH2O 0.7 330 0.1 4.2 1.912 165 24.50 5.225 74
V2O5 0.72 460 0.5 2.0 1.269 212 17.7 3.61 75

aThe anode mass loading is balanced with the cathode by using Zn powder instead of foil.