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. Author manuscript; available in PMC: 2020 Mar 9.
Published in final edited form as: J Am Chem Soc. 2019 Apr 1;141(14):5788–5797. doi: 10.1021/jacs.8b13157

Figure 4.

Figure 4.

A) Chromatogram displaying the single-ion monitoring (SIM) of the dominant product formed when 1 mM compound 7 is incubated with 1 mM SAM, 50 μM NosN and 2 mM Ti(III) citrate for 1 h. B) MS spectrum of NosN product of compound 7 using SAM (red trace) or [13C methyl]SAM (blue trace). C) MS/MS analysis of NosN product of compound 7 using SAM (red trace) or [13C methyl]SAM (blue trace).