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. Author manuscript; available in PMC: 2020 Mar 9.
Published in final edited form as: J Am Chem Soc. 2019 Apr 1;141(14):5788–5797. doi: 10.1021/jacs.8b13157

Figure 5.

Figure 5.

(A) NosN-catalyzed formation of SAH and a SAM adduct in the presence of compound 7 (black circles) and compound 8 (red circles). Green circles represent a SAM-adduct that decomposes to SAH in the mass spectrometer when using compound 8. (B) NosN-catalyzed formation of 5’-dA in the presence of compound 7 (black circles) and compound 8 (red circles). Each reaction contained 1 mM compound 7 or compound 8, 2 mM Ti(III) citrate, and 50 μM NosN, and was initiated with 1 mM SAM.