Table 3. Electrochemical Properties Data and Molecular Energy Levels of PTK, PBTK, and PFTK.
| polymer | E1/2red (V) | LUMO (eV)a | HOMO (eV)b | LUMO (eV)c | HOMO (eV)c |
|---|---|---|---|---|---|
| PTK | –1.81 | –2.99 | –5.50 | –2.91 | –6.30 |
| PBTK | –1.76 | –3.04 | –5.34 | –3.19 | –6.26 |
| PFTK | –1.86 | –2.94 | –5.30 | –2.89 | –5.91 |
Calculated from CV: ELUMO = −(4.80 + E1/2red) eV.
Calculated from ELUMO and Egopt.: EHOMO = ELUMO − Eg.
The DFT calculation data.