Table 2.

Comparison of the catalytic reaction yields and useful geometric parameters, derived from solid-state structural data. Values in () indicate yields based on congener with complementary oxidation state to the species used for catalysis.

Fig. 7	Complex (Coord Geometry)	Catalytic Yield	Mn+	ar (pm)	Nax-Fe-Nax Angle (°)	Neq-Fe-Neq Angle (°)	Cl-Fe-Cl Angle (°)	Cl-Cl Bond Dist (Å)	M-N Bond Dist (Å)	M-Cl Bond Dist (Å)	Ref
a	[Fe2+L7(Cl)2]+ (Octahedral)	(74)	Fe2+	92	145.78	77.31	93.42	3.511	2.276	2.416	35
									2.269
										2.407
									2.248
									2.240
b	[Fe2+L8(Cl)2] (Octahedral)	(68)	Fe2+	92	161.88	78.36	95.53	3.593	2.275	2.426	35
									2.287
									2.257	2.427
									2.263
c	[Fe3+L7(Cl)2]+ (Octahedral)	74	Fe3+	79	153.20	77.81	95.10	3.377	2.179	2.2853	98
									2.158
									2.171
									2.163	2.2911
d	[Fe3+L8(Cl)2]+ (Octahedral)	68	Fe3+	79	166.8	79.8	95.70	3.412	2.188	2.278	99
									2.197
									2.223	2.288
									2.229
e	[Fe2+L5Cl]+ (Square Pyramidal (τ) = 0.098b)	30	Fe2+	92	131.14	125.27	-	-	2.296	2.304	This work
									2.278
									2.228
									2.232
f	[Fe2+L6(Cl)2] (Octahedral)	81	Fe2+	92	162.4	91.5	94.4	3.58	2.27	2.438	This work
									2.31	2.438
g	[Fe3+L1(Cl)2]+ (Octahedral)	57	Fe3+	79	146.68	86.62	95.78	3.388	2.181	2.2862	This work
									2.182
									2.161	2.2805
									2.098(Npy)
h	[Fe2+L10(Cl)]+ (Octahedral)	19	Fe2+	92	168.27	80.82	-	-	2.204	2.3805	66
									2.232
									2.246
									2.285
									2.215(Npy)

^aShannon, R. D. Acta Crystallogr. Sect. A 1976, 32, 751–767.

^bAddison, A. W. et al. J Chem Soc Dalton 1984, 7, 1349–1356.